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MSDS for Tetraborato de Sodio

Identification

Product Name: Tetraborato de Sodio
Synonyms: Sodium Tetraborate, Borax, Disodium Tetraborate Decahydrate
Chemical Formula: Na2B4O7·10H2O
CAS Number: 1303-96-4
EC Number: 215-540-4
Recommended Use: Water softener, cleaning agent, component for glass and ceramics, buffer solutions
Manufacturer/Supplier Identification: Name, Address, Emergency Telephone Number, Email (company-specific)
Emergency Phone: Local Poison Control/Fire Department contacts

Hazard Identification

GHS Classification: Reproductive Toxicity Category 1B, Eye Irritation Category 2
Signal Word: Danger
Hazard Statements: May damage fertility or the unborn child (H360), Causes serious eye irritation (H319)
Precautionary Statements: Wear protective gloves and eye protection, avoid breathing dust, wash hands thoroughly after handling, obtain special instructions before use
Health Effects: Eye irritation, possible effects on reproduction with chronic or high-level exposure, possible skin dryness
Environmental Impact: May not rapidly degrade but is not classified as environmentally hazardous in most use scenarios

Composition / Information on Ingredients

Chemical Name: Sodium Tetraborate Decahydrate
Concentration: 99-100%
CAS Number: 1303-96-4
Impurities: Less than 1% trace impurities not classified as hazardous

First Aid Measures

Inhalation: Move affected person to fresh air, loosen any tight clothing, seek medical advice if symptoms persist such as coughing, wheezing, or shortness of breath
Skin Contact: Wash skin with plenty of water and soap, remove contaminated clothing, seek medical attention if irritation or rash develops
Eye Contact: Rinse cautiously with water for at least 15 minutes while holding eyelids open, remove contact lenses before rinsing, continue rinsing, seek medical evaluation for persistent irritation or pain
Ingestion: If swallowed, rinse mouth with water, do not induce vomiting, drink water to dilute if conscious, seek immediate medical help for large quantities or persistent symptoms

Fire-Fighting Measures

Suitable Extinguishing Media: Water spray, dry chemical powder, foam, carbon dioxide; cool containers with water spray to prevent bursting if exposed to flames
Unsuitable Media: None known for sodium tetraborate
Specific Hazards: Non-flammable, does not emit flammable vapors; at high temperatures, may emit irritating or toxic fumes such as boron oxides
Protective Equipment for Firefighters: Full protective gear and self-contained breathing apparatus recommended in case of fire involving nearby combustibles
Firefighting Instructions: Avoid breathing dust or fumes, isolate area and keep out unnecessary personnel; cool exposed containers

Accidental Release Measures

Personal Precautions: Use dust mask, chemical-resistant gloves, eye protection, avoid contact with skin and eyes, ventilate area
Spill Containment: Avoid generating airborne dust, sweep up carefully and place in labeled containers, avoid uncontrolled release into sewage, soil, or waterways
Clean-Up Methods: Vacuum or wet-sweep for large spills, wash spill site after material pickup, prevent further release or spread
Disposal: Dispose of collected material according to local, national, or regional environmental regulations

Handling and Storage

Safe Handling Instructions: Avoid dust generation and inhalation, do not eat or drink while handling, wash thoroughly after use, use only with adequate ventilation
Storage Recommendations: Store in tightly closed containers, keep in a cool, dry, well-ventilated area, avoid exposure to moisture or water, store away from acids
Technical Measures: Use appropriate containers to prevent moisture ingress and maintain product integrity
Incompatible Materials: Acids and strong oxidizing agents, which may generate heat or hazardous gases

Exposure Controls and Personal Protection

Exposure Limits: OSHA PEL: 10 mg/m3 (total dust), 5 mg/m3 (respirable fraction); ACGIH TLV: 2 mg/m3 (inhalable borate dust)
Engineering Controls: Local exhaust ventilation, process enclosures, dust collection systems to control airborne dust
Personal Protective Equipment: Dust mask or respirator (for high dust levels), chemical-resistant gloves (nitrile, neoprene), safety goggles, protective clothing as needed
Hygiene Measures: Wash hands and face after handling, change contaminated clothing, do not use near food or beverages

Physical and Chemical Properties

Appearance: White, odorless crystalline solid or powder
Odor: Odorless
Solubility in Water: Soluble (approx. 50 g/L at 20°C)
pH (1% solution): About 9.2
Melting Point: 741°C (anhydrous), dehydrates at lower temperatures
Boiling Point: Decomposes before boiling
Vapor Pressure: Not applicable (non-volatile)
Density: Approximately 1.7 g/cm3 (decahydrate)
Flash Point: Not flammable

Stability and Reactivity

Chemical Stability: Stable under recommended storage and handling conditions
Thermal Decomposition: May decompose at high temperatures to boron oxides and water
Reactivity: Reacts with strong acids to release boric acid and heat
Conditions to Avoid: Moisture, exposure to acids, prolonged exposure to air, excessive heat
Incompatible Materials: Acids, strong oxidizers
Hazardous Decomposition Products: Boron oxides, sodium oxide fumes if heated to decomposition

Toxicological Information

Acute Toxicity: Oral LD50 (rat): about 2660 mg/kg; skin and eye irritation possible
Chronic Toxicity: Repeated or prolonged exposure by inhalation or ingestion may affect reproductive organs, possible influence on fertility with long-term exposures above regulatory limits
Routes of Exposure: Inhalation, ingestion, skin and eye contact
Symptoms of Overexposure: Eye redness, burning sensation, dry or cracked skin, stomach upset with high amounts ingested
Carcinogenicity: Not classified as carcinogenic by IARC, NTP, OSHA
Mutagenicity/Teratogenicity: Classified as possible hazard to fertility or unborn child with significant, long-term exposure

Ecological Information

Aquatic Toxicity: Moderately toxic to aquatic life in high concentrations; aquatic LC50 for fish: approximately 100-200 mg/L
Persistence and Degradability: Borates occur naturally, do not degrade rapidly, and move through soil and water
Bioaccumulation: Not expected in aquatic organisms
Mobility in Soil: Water soluble, readily moves with runoff
Other Ecological Effects: Plants exposed to high levels may show growth inhibition; significant soil release can alter pH

Disposal Considerations

Waste Disposal Methods: Dispose of material in accordance with local, state, and federal regulations, preferably in designated chemical waste facilities
Contaminated Packaging: Containers should be emptied completely and can be recycled or disposed of as per regional guidelines
Special Instructions: Avoid disposal into surface water or drains; do not incinerate

Transport Information

UN Number: Not regulated as a hazardous material for transport under UN, ADR, IATA, IMDG rules
Proper Shipping Name: Sodium Tetraborate, not classified as hazardous for transport
Hazard Class: None
Packing Group: None
Label: None required
Environmental Hazards: No significant environmental hazard under common transport conditions
Special Transport Precautions: Keep containers secure to prevent spillage, avoid water contact during transit

Regulatory Information

OSHA: Classified as hazardous under OSHA Hazard Communication Standard
TSCA Status (US): Listed in TSCA Inventory
REACH (EU): Registered substance, subject to authorization for some uses as a substance of very high concern (SVHC)
WHMIS (Canada): Class D2A, D2B (toxic materials)
SARA 313: Not listed
California Proposition 65: Not specifically listed
Other International Regulations: Subject to local and regional requirements for chemical control and environmental protection