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MSDS of SUPELPURE HC REFILL

Identification

Product Name: SUPELPURE HC REFILL
Supplier/Manufacturer: Supelco, part of MilliporeSigma
Product Use: Laboratory purification material for hydrocarbon applications
Contact Information: Customer support, Safety officer’s direct phone, Emergency telephone (Chemtrec/National Poison Center)
Recommended Restrictions: Laboratory use only, not for diagnostic or therapeutic procedures

Hazard Identification

GHS Classification: Not considered hazardous by GHS criteria for pure substance
Main Health Hazards: Dust inhalation, skin or eye irritation in sensitive individuals
Physical Hazards: Fine particles may cause dust clouds
Status Under Other Standards: Not listed as carcinogen by NTP, IARC, or OSHA
GHS Label Elements: No symbol or signal word required for non-hazardous material
Precautionary Statements: Avoid breathing dust, wash hands after handling

Composition / Information on Ingredients

Chemical Nature: Solid adsorbent, proprietary mixture
Main Component: Highly purified hydrocarbon adsorber, proprietary polymer base
CAS Number: Confidential due to proprietary status
Percentage: 100% active adsorbent, no major non-functional fillers
Impurities: Trace inorganic residue less than 0.1%

First Aid Measures

Eyes: Flush with clean running water for 15 minutes, remove contacts if easy, seek care if irritation continues
Skin: Wash with soap and water, remove contaminated clothing, consult physician if rash or discomfort develops
Inhalation: Move person to fresh air, seek support for persistent coughing or breathing irritation
Ingestion: Rinse out mouth, give water to drink, seek medical attention if discomfort persists or large amounts ingested
Immediate Attention: Rarely required, seek further help if unusual symptoms develop after exposure

Fire-Fighting Measures

Suitable Extinguishing Media: Water spray, dry chemical, CO2, foam
Hazardous Combustion Products: Carbon monoxide, carbon dioxide, possible hydrocarbons
Special Firefighting Procedures: Use self-contained breathing apparatus, full turnout gear
Unusual Fire Hazards: May produce fine combustible dust, avoid generating clouds
Explosion Data: Dust deposits can ignite under certain conditions

Accidental Release Measures

Personal Precautions: Wear gloves and dust mask for large spills
Containment: Avoid dust generation, collect spilled material with clean, dry tools
Cleanup: Sweep into suitable container for disposal, wash area after pickup
Environmental Precautions: Prevent material from entering drains, avoid release to surface water
Disposal Recommendations: Store in closed, labeled containers until disposal steps can follow local or facility protocols

Handling and Storage

Handling Practices: Use with adequate ventilation, minimize creation of dust
PPE Required: Gloves, safety goggles during transfers
Safe Storage Conditions: Store in airtight container, cool, dry, well-ventilated place
Segregation: Keep separate from acids, strong oxidizers, food and beverages
Spill Preparedness: Keep spill kit with dust masks nearby in storage areas

Exposure Controls and Personal Protection

Occupational Exposure Limits: No established OSHA or ACGIH limits for this mixture
Engineering Controls: Use fume hood or local exhaust where practical
Personal Protection: Respirator (N95 or similar) if handling large quantities as dry powder, chemical safety glasses, nitrile gloves
Hygiene Measures: Wash thoroughly after handling, do not eat or drink during use
Eye/Hand/Body Protection: Splash goggles or face shield, lab coat for repeated or large-quantity handling

Physical and Chemical Properties

Appearance: White to off-white granular or bead solid
Odor: Odorless
pH: Neutral in water
Melting/Freezing Point: Not applicable, decomposes at high temperature
Boiling Point: Not applicable
Flash Point: Not applicable
Flammability: Non-flammable as sold, fine powders may burn as dust
Solubility: Insoluble in water and common solvents
Bulk Density: 0.45–0.65 g/cm3
Partition Coefficient: N/A (insoluble)
Vapor Pressure: Not applicable, non-volatile
Decomposition Temperature: Above 240°C

Stability and Reactivity

Chemical Stability: Stable under normal handling and storage conditions
Conditions to Avoid: Excess moisture, direct sunlight, strong heat above 200°C
Incompatible Materials: Strong acids, oxidizing agents
Hazardous Polymerization: Will not occur
Hazardous Decomposition: Oxides of carbon, hydrocarbons on burning

Toxicological Information

Acute Toxicity: No data suggest significant acute effects for skin, inhalation, or ingestion
Chronic Toxicity: Not expected due to inertness; dust may cause minor respiratory or skin irritation with long-term, repeated overexposure
Possible Routes of Exposure: Inhalation of dust, skin/eye contact, incidental ingestion
Carcinogenicity: Components not listed as carcinogenic by IARC, NTP, or OSHA
Other Effects: Dust may exacerbate pre-existing lung conditions in sensitive persons

Ecological Information

Ecotoxicity: Not expected to be hazardous to aquatic life due to insolubility
Persistence and Degradability: Stable, not readily biodegradable
Bioaccumulative Potential: No potential for bioaccumulation
Mobility in Soil: Immobile, material settles in sediment
Other Adverse Effects: None expected outside of physical obstruction in aquatic environments

Disposal Considerations

Waste Disposal Methods: Manage as non-hazardous solid industrial waste, landfill or incinerate according to local, state, and federal regulations
Do Not: Flush to drain, mix with incompatible waste
RCRA Status: Not considered hazardous waste under present regulations
Packaging: Triple rinse containers before recycling or disposal, if required by local guidelines
Precautions: Minimize dust release during disposal steps

Transport Information

UN Number: None assigned
Proper Shipping Name: Not regulated as dangerous goods for transport
Hazard Class: Not applicable
Packing Group: Not applicable
Special Precautions for Users: Use clean packaging, keep sealed, label clearly
Transport in Bulk: Not regulated in bulk transport
Other Info: Follow local, national, and international requirements for chemical shipments

Regulatory Information

Inventory Listings: Components appear on TSCA and REACH inventories
SARA Title III: Not subject to Section 313 reporting, not listed as extremely hazardous
California Proposition 65: Contains no chemicals known to the State of California to cause cancer or reproductive toxicity
WHMIS (Canada): Not regulated
RoHS Compliance: Meets criteria, no restricted substances
Other Regulatory Info: Material is classified as an article in some jurisdictions, limiting reporting requirements; refresh local, state, or on-site documentation annually