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Material Safety Data Sheet: Sodium Hydrogen Tartrate

Identification

Product Name: Sodium Hydrogen Tartrate
Synonyms: Monosodium tartrate, Sodium bitartrate
Chemical Formula: NaHC4H4O6
Molecular Weight: 188.06 g/mol
CAS Number: 868-18-8
Recommended Uses: Used in laboratories, food additives, pH control, cleaning agents, and stabilizers.
Manufacturer Information: Detailed contact information for chemical supplier or distributor. Includes emergency telephone number, available 24-hours if available, and an address for future correspondence regarding safety, transport, or regulatory queries.

Hazard Identification

GHS Classification: Not classified as hazardous under GHS standards
Signal Word: None
Hazard Statements: May cause mild irritation to eyes and skin on contact. Large quantities can lead to gastrointestinal distress if ingested.
Precautionary Statements: Avoid creating dust. Use personal protective equipment to minimize skin and eye contact. Wash hands thoroughly after handling.
Medical Conditions Aggravated by Exposure: Existing skin, eye, or respiratory conditions may worsen with prolonged exposure to dust.
Label Elements: No pictograms required by GHS. Safety phrase: Handle with care and avoid contact with sensitive areas.

Composition / Information on Ingredients

Chemical Name: Sodium Hydrogen Tartrate
Common Name: Sodium Bitartrate
Concentration: ≥ 99% by weight
Impurities: Trace amounts of water, tartaric acid, or related salts as manufacturing byproducts. Normally present below reportable thresholds.
CAS Number: 868-18-8
EC Number: 212-769-1

First Aid Measures

Inhalation: Remove person to fresh air. Seek medical attention if breathing difficulties or persistent symptoms appear. Loosen tight clothing if any discomfort.
Eye Contact: Rinse cautiously with water for several minutes. Remove contact lenses if present. Keep eyes open during rinsing.
Skin Contact: Wash thoroughly with mild soap and water. Remove contaminated clothing. Contact healthcare professional if irritation persists.
Ingestion: Rinse mouth with water. Do not induce vomiting. If significant amounts are swallowed or symptoms like nausea, vomiting, or abdominal pain develop, seek immediate medical attention.
Advice for First Responders: Provide symptomatic treatment. Use protective gloves and goggles when administering care to prevent cross-exposure.

Fire-Fighting Measures

Suitable Extinguishing Media: Water spray, foam, dry chemical, or carbon dioxide. Select extinguishing media based on surrounding fire.
Specific Hazards: Decomposition in fires may release irritating fumes of sodium oxides and organic acids. Dust accumulation can cause local combustion if exposed to open flames or high temperatures.
Special Protective Equipment: Firefighters should wear self-contained breathing apparatus and full protective gear.
Advice for Firefighters: Move containers from fire area if possible without risk. Keep area clear of unnecessary personnel.

Accidental Release Measures

Personal Precautions: Wear suitable protective equipment such as gloves, goggles, and masks to prevent dust inhalation. Ventilate area.
Environmental Precautions: Avoid release to the environment. Prevent powder from entering waterways or sewage systems.
Methods for Cleanup: Carefully sweep up and shovel spilled material. Place in a labeled container for proper disposal. Wash spill area with water to remove residues.
Reference to Other Sections: Refer to “Personal Protection” and “Disposal” sections for further specific actions and handling.

Handling and Storage

Safe Handling Procedures: Handle with adequate ventilation. Minimize dust generation and accumulation. Do not eat, drink, or smoke while using this product. Use personal protective equipment as needed.
Storage Conditions: Store in a tightly closed container in a cool, dry, well-ventilated area away from incompatible substances like strong bases or oxidizers. Keep away from moisture to prevent caking.
Incompatibilities: Avoid contact with strong bases, oxidizers, or reducing agents. These can cause decomposition or hazardous reactions.
Special Requirements: Use local exhaust for dusty operations. Label containers clearly with product identifier.

Exposure Controls and Personal Protection

Occupational Exposure Limits: No established exposure limits for sodium hydrogen tartrate. Use general dust control limits (ACGIH TLV for particulates not otherwise classified: 10 mg/m³ (total), 3 mg/m³ (respirable)).
Engineering Controls: Use exhaust ventilation or process enclosure to minimize airborne dust levels. Maintain eyewash stations and safety showers in proximity.
Personal Protective Equipment: Wear chemical-resistant gloves, safety goggles, and dust masks or NIOSH-approved respirators during handling. Use lab coats or coveralls to protect skin.
Hygiene Measures: Always wash hands, forearms, and face after handling and before eating or drinking.

Physical and Chemical Properties

Appearance: White to colorless crystalline powder
Odor: Odorless
Odor Threshold: Not applicable
pH: Approximately 3.5 (1% solution)
Melting Point/Freezing Point: Decomposes before melting, typically above 100°C
Boiling Point: Not applicable (decomposes)
Flash Point: Not applicable
Evaporation Rate: Not applicable
Flammability: Not flammable
Explosive Properties: Not explosive
Vapor Pressure: Not available
Vapor Density: Not available
Relative Density: 1.79 g/cm³
Solubility: Soluble in water
Partition Coefficient (n-octanol/water): Not determined
Auto-Ignition Temperature: Not self-igniting
Decomposition Temperature: Above 100°C
Viscosity: Not applicable
Other Characteristics: Forms acidic solution in water, may absorb moisture from air.

Stability and Reactivity

Chemical Stability: Stable under normal temperatures and pressures when stored dry.
Conditions to Avoid: Avoid moisture, excessive heat, and contact with incompatible substances.
Incompatible Materials: Strong bases, oxidizers, and reducing agents.
Hazardous Decomposition Products: On heating or during fire may release sodium oxides, organic acids, and carbon oxides.
Possibility of Hazardous Reactions: No dangerous reactions known under recommended storage and handling conditions.

Toxicological Information

Acute Toxicity: Oral LD50 (rat): >2000 mg/kg
Skin Corrosion/Irritation: Mild irritation possible with prolonged or repeated skin contact.
Serious Eye Damage/Irritation: May cause redness or discomfort in unprotected eyes.
Respiratory or Skin Sensitization: Not expected to be a sensitizer.
Germ Cell Mutagenicity: Not classified as a mutagen.
Carcinogenicity: Not listed as carcinogenic by OSHA, NTP, IARC or ACGIH.
Reproductive Toxicity: No data showing reproductive hazard.
STOT-Single Exposure: Not classified for target organ toxicity with single exposure.
STOT-Repeated Exposure: Not classified for target organ toxicity with repeated exposure.
Aspiration Hazard: No known aspiration hazard.
Other Information: Ingestion of large amounts may result in gastrointestinal upset.

Ecological Information

Ecotoxicity: Not considered toxic to aquatic life based on low environmental impact at incidental release concentrations.
Persistence and Degradability: Readily biodegradable. Breaks down in the environment by natural processes.
Bioaccumulative Potential: Low potential, based on mobility and water solubility.
Mobility in Soil: Mobile in the environment due to solubility. May move rapidly through soil if spilled.
Other Adverse Effects: No reported evidence of hazard to ecosystems under typical use and disposal practices.

Disposal Considerations

Waste Treatment Methods: Dispose of in accordance with local, state, and federal regulations. Sweep up material and deliver to authorized chemical disposal facility.
Contaminated Packaging: Rinse containers before recycling or disposal. Follow disposal directions from authorities for packaging that may have contained hazardous materials.
Special Considerations: Do not discharge product into public waterways, drains, or soil in large quantities. Seek advice from authorities in case of bulk spills.

Transport Information

UN Number: Not classified as dangerous for transport.
UN Proper Shipping Name: Not regulated.
Transport Hazard Class: Not applicable.
Packing Group: Not applicable.
Environmental Hazards: Not classified as a marine pollutant.
Special Precautions: No special requirements. Avoid transport with incompatible substances (e.g., strong oxidizers or acids) to prevent accidental reaction.
Other Transport Information: Ensure secure container closure to prevent accidental release during transportation.

Regulatory Information

Safety, Health and Environmental Regulations: Not subject to OSHA specific regulation for hazardous chemicals. Not on EPA Extremely Hazardous Substances List. Not regulated as a food safety risk under FDA when used as intended.
TSCA Status: Listed on the U.S. Toxic Substances Control Act inventory.
EU Regulations: REACH registration not required for substances used in research or exempted processes. Not classified as hazardous under EU CLP guidelines.
Canadian DSL/NDSL: Present on Domestic Substance List.
Other Details: Review national and local regulations for applicable workplace labeling or waste management practices.