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Material Safety Data Sheet: METOXI 2 PROPANOL (C4H10O2)

Identification

Product Name: METOXI 2 PROPANOL
Chemical Formula: C4H10O2
Synonyms: 2-Methoxypropanol, Propylene glycol monomethyl ether, PGME
CAS Number: 107-98-2
Recommended Use: Used as solvent in coatings, inks, cleaning agents, adhesives, electronics, and chemical synthesis
Manufacturer: [Specify manufacturer details]
Emergency Contact: [Provide local emergency phone number]
UN Number: 3092

Hazard Identification

GHS Classification: Flammable liquid (Category 3), Acute toxicity (Category 4), Eye irritation (Category 2A), Specific target organ toxicity - single exposure (Category 3, narcotic effects)
Signal Word: Warning
Hazard Statements: Flammable liquid and vapor, Causes serious eye irritation, Harmful if inhaled or swallowed, May cause drowsiness or dizziness
Pictograms: Flame, Exclamation mark
Precautionary Statements: Keep away from heat, sparks, open flames, and hot surfaces. Avoid breathing vapors. Wear eye and face protection. Avoid contact with eyes and skin. Use only in well-ventilated areas.

Composition / Information on Ingredients

Chemical Name: 2-Methoxy-1-propanol
Common Name: METOXI 2 PROPANOL
CAS Number: 107-98-2
Concentration: 98-100%
Impurities: None of significance for occupational exposure
Stabilizing Additives: None reported

First Aid Measures

General Advice: Move affected individual from area of exposure to fresh air. Seek immediate medical attention if symptoms persist.
Inhalation: Remove to fresh air. Provide artificial respiration if breathing has stopped. Monitor for respiratory distress.
Skin Contact: Remove contaminated clothing. Wash exposed skin with soap and water. Seek medical evaluation for irritation, redness, or burns.
Eye Contact: Rinse cautiously with water for several minutes; remove contact lenses if present and easy to do. Continue rinsing. Seek medical attention for persistent irritation.
Ingestion: Rinse mouth. Do not induce vomiting unless directed by medical personnel. Never provide anything by mouth to an unconscious person. Immediate medical intervention recommended.

Fire-Fighting Measures

Suitable Extinguishing Media: Use dry chemical, CO2, alcohol-resistant foam, or water spray. Water jets may spread fire
Specific Hazards: Vapors can form explosive mixtures with air. Containers may explode when heated. Combustion produces toxic gases (carbon monoxide, carbon dioxide)
Protective Equipment: Firefighters should wear self-contained breathing apparatus and full protective fire-resistant clothing
Advice for Firefighters: Evacuate surrounding area. Cool containers with water spray to prevent pressure build-up. Prevent runoff from entering drains or waterways.

Accidental Release Measures

Personal Precautions: Evacuate unprotected personnel. Ensure adequate ventilation. Remove dust and ignition sources. Avoid breathing vapor, mist, or gas. Wear protective equipment including gloves, goggles, and respirator.
Environmental Precautions: Prevent entry into sewers, drains, or waterways. Notify authorities if product enters the environment.
Methods for Cleanup: Contain spill with sand, inert absorbent material, or non-combustible material. Use spark-proof tools. Store collected material in properly labeled containers for disposal following local regulations.

Handling and Storage

Precautions for Safe Handling: Work in well-ventilated areas. Avoid inhaling vapors. Wash hands thoroughly after handling. Prevent buildup of static electricity by grounding and bonding containers and equipment. Do not eat, drink, or smoke during use.
Conditions for Safe Storage: Store in cool, dry, well-ventilated area away from heat and sunlight. Keep containers tightly closed when not in use. Store away from oxidizers, acids, and ignition sources.
Special Requirements: Use explosion-proof electrical equipment. Maintain storage temperature below flashpoint.

Exposure Controls and Personal Protection

Occupational Exposure Limit: ACGIH TLV: 100 ppm (369 mg/m³), STEL: 150 ppm (553 mg/m³)
Engineering Controls: Use local exhaust ventilation or other engineering controls to maintain airborne concentrations below recommended limits
Personal Protective Equipment: - Respiratory Protection: Approved respirator for organic vapors if above occupational limits
- Hand Protection: Impervious gloves such as nitrile
- Eye Protection: Chemical safety goggles
- Skin Protection: Protective clothing (lab coat, coveralls)
Hygiene Measures: Wash hands and face after handling. Remove contaminated clothing before re-use.

Physical and Chemical Properties

Appearance: Colorless liquid
Odor: Mild ether-like
Odor Threshold: 10-50 ppm
pH: Not applicable
Melting Point/Freezing Point: -96°C
Boiling Point/Range: 120°C
Flash Point: 31°C (closed cup)
Evaporation Rate: 0.6 (butyl acetate=1)
Flammability: Flammable
Upper/Lower Flammability or Explosive Limits: Lower: 1.5%, Upper: 13.1%
Vapor Pressure: 9.8 mm Hg @ 20°C
Vapor Density: 3.1 (air=1)
Relative Density: 0.92 (water=1)
Solubility: Miscible with water and most organic solvents
Partition Coefficient (n-octanol/water): -0.437
Auto-ignition Temperature: 315°C
Decomposition Temperature: Not determined
Viscosity: 2.2 mPa.s at 25°C

Stability and Reactivity

Chemical Stability: Stable under recommended storage conditions. Sensitive to air and light over extended periods.
Possibility of Hazardous Reactions: Can react with strong oxidizers, acids, and alkali metals. Vapors may form explosive mixtures with air.
Conditions to Avoid: Avoid sources of heat, sparks, flame, and static discharge. Avoid prolonged exposure to air.
Incompatible Materials: Oxidizing agents, strong acids, strong alkalis
Hazardous Decomposition Products: Carbon monoxide, carbon dioxide, irritating fumes on combustion

Toxicological Information

Acute Toxicity: Oral LD50 (rat): 4016 mg/kg
Inhalation LC50 (rat, 4h): 6,000 ppm
Dermal LD50 (rabbit): 13,000 mg/kg
Skin Irritation: Mild irritation possible
Eye Irritation: Moderate to severe irritation
Sensitization: Not classified as skin sensitizer
Other Effects: Drowsiness, dizziness, headache, and nausea at high concentrations
Chronic Effects: Prolonged or repeated exposure may affect central nervous system, liver, and kidneys
Carcinogenicity/Mutagenicity: Not considered carcinogenic or mutagenic by major agencies
Reproductive Toxicity: No evidence of reproductive harm

Ecological Information

Ecotoxicity: Aquatic toxicity data: LC50 (Fish, 96 h): 20,800 mg/L
Persistence and Degradability: Readily biodegradable in water and soil
Bioaccumulative Potential: Low log Kow value indicates low potential for bioaccumulation
Mobility in Soil: High, likely to penetrate soil and affect groundwater
Other Adverse Effects: Large spills may cause negative effects due to oxygen depletion in aquatic systems
Environmental Precautions: Prevent uncontrolled release to environment

Disposal Considerations

Waste Treatment Methods: Treat as hazardous waste. Incinerate in chemical incinerator with afterburner and scrubber or hand over to licensed waste disposal company.
Contaminated Packaging: Empty containers must be triple rinsed and sent for disposal according to local regulations.
Disposal Regulations: Dispose of in accordance with federal, state, and local environmental control regulations.
Special Precautions: Do not flush into surface water or sanitary sewer system. Avoid landfilling liquids.

Transport Information

UN Number: 3092
Proper Shipping Name: 2-Methoxy-1-propanol
Transport Hazard Class: 3 (Flammable liquid)
Packing Group: III
Marine Pollutant: No
Special Precautions: Keep away from foodstuffs, acids, and alkalis during transport. Use appropriate containers clearly labeled and tightly closed. Avoid conditions leading to spillage or leaks.

Regulatory Information

TSCA: Listed on the United States TSCA inventory
OSHA: Hazardous Chemical, as defined by OSHA Hazard Communication Standard
SARA Title III Sections 311/312: Fire hazard, Immediate health hazard
REACH: Registered under REACH regulation, subject to restrictions in some countries
Canada WHMIS Classification: B3 (Flammable Liquids), D2B (Toxic Material causing other toxic effects)
California Proposition 65: Not listed
Other Information: Check regional regulations to ensure compliance as laws may vary for transport, storage, and disposal