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Malonaldehyde bis(dimethyl acetal) didn’t just show up in a catalog one day. Its emergence links back to the creativity and demands of synthetic chemistry in the mid-20th century, a period marked by rapid advances in organic synthesis. Chemists sought alternatives for handling reactive and sometimes fickle dicarbonyl compounds like malonaldehyde itself, which is notorious for instability. Acyclic acetals arrived as a workaround, offering a path to mask the reactive carbonyls for smoother handling and selective reactions. Malonaldehyde bis(dimethyl acetal), sometimes called MBDMA, entered literature during this exploratory stage, as researchers identified the need for new routes to important synthons. For anyone who has worked at the bench, these stories reflect countless experiments: nothing flashy, just persistent attempts to tame wily molecules for broader application.
At first glance, malonaldehyde bis(dimethyl acetal) looks like a colorless to pale yellow liquid, boiling with a rather distinct aroma that perfumes the synthetic lab during distillation. Its structure cloaks malonaldehyde’s dialdehyde core inside a pair of stable dimethyl acetal groups. Unlike its parent molecule, malonaldehyde, it resists polymerization and decomposition when stored under proper conditions. That stability counts: try getting good yields out of even a simple nucleophilic addition when your core building block decomposes faster than you can set up a flask. I remember my own frustration with dialdehydes seizing up the reaction mixture, so stumbling onto acetals like this was a relief.
Malonaldehyde bis(dimethyl acetal) possesses a boiling point around 120°C at reduced pressure, and it mixes with most common solvents. Its density sits in the range familiar to liquid acetals. In the lab, it resists moisture up to a point, though open-air contact leads to slow hydrolysis. Chemically, it acts as an acetal—stable in neutral and mildly basic media, yet sensitive to acids. Anyone who has spilled a little on a benchtop and returned some hours later will attest to the formation of a sticky residue as hydrolysis peels away acetal groups, yielding back malonaldehyde. In practice, careful storage under dry, inert atmosphere prevails.
Chemists don’t obsess over brands; they focus on content and purity. MBDMA often arrives labeled with purity ratings above 97%, flagged for potential impurities such as dimethyl acetal or residual dichloromethane from purification. The regulatory classification tags it as an irritant and moderate hazard—direct contact with skin or inhalation should be avoided, even though it lacks the extreme volatility of some acrolein derivatives. In the real world, that translates to fume hoods, gloves, and cautious weighing, routines ingrained in every chemistry graduate student. Regulatory changes push for improved handling, and producers will often include guidance consistent with OSHA and REACH guidelines, reflecting a growing awareness of chemical stewardship.
Synthesizing malonaldehyde bis(dimethyl acetal) offers a textbook exercise in classical organic transformations. Most routes begin with malonaldehyde precursors, progressing via acid-catalyzed reaction with methanol. Fisher projections and curved-arrow mechanisms come to life in the mind’s eye: the proton-shuttled acetalization of malonaldehyde with two equivalents of methanol, often in the presence of an acid such as p-toluenesulfonic acid. Removal of water—either by azeotropic distillation or use of molecular sieves—drives the equilibrium. Practical chemists fine-tune conditions for yield and purity. The byproducts often haunt the work-up stage, as lingering acids and partially converted aldehydes complicate purification.
Malonaldehyde bis(dimethyl acetal) shines as a masked malonaldehyde: stable during many reactions, yet ready to release its reactive core under acidic conditions. This property opens doors to all sorts of synthetic transformations. Acid treatment cleaves the acetal, reinstalling the free aldehydes. Synthetic chemists exploit this as a protective group, conducting multi-step syntheses in the presence of reagents that would obliterate a bare aldehyde. From the construction of heterocycles to fine-tuning the introduction of alkyl chains, MBDMA serves as a controlled precursor. Its nucleophilic and electrophilic handles permit aldol-type condensations or cyclizations, steps that feature in the synthesis of biologically active molecules. Each reaction offers learning opportunities—walk into any research lab, and you see its tributaries flowing into new pharmaceuticals or specialty polymers.
In catalogs and chemistry journals, the compound appears as malonaldehyde bis(dimethyl acetal), but the world of synonyms rarely gets simple. Names like 1,1,3,3-tetramethoxypropane or tetramethoxymethane can cause confusion unless the structure is checked. Over the years I’ve fumbled an order more than once due to ambiguous catalog entries, underscoring why standardization matters. The chemical structure—a three-carbon chain with two dimethoxy groups attached to terminal carbons—shows up under various nomenclatures in the literature. For anyone tracking down historical syntheses or product entries, cross-verifying a CAS number proves more reliable than relying on local labels.
On the safety front, MBDMA rates as less dramatic than many lab solvents, but its irritant properties command respect. Splash-proof goggles, clean gloves, and a functional fume hood define the baseline setup. Once I had a colleague who brushed off a minor spill, only to develop mild dermatitis and a sore throat the next day—a sobering reminder that “moderate hazard” labels still mark danger. The chemical’s low acute toxicity often lulls users into complacency, but consistent good practices trump assumptions. Mixing, transferring, and heating acetal compounds in closed systems helps control exposure, and storage in amber glass under nitrogen prevents both hydrolysis and photo-induced breakdown.
Malonaldehyde bis(dimethyl acetal) finds its way into many corners of the chemical industry. Where pharmaceutical manufacturers turn dialdehydes and related building blocks into anti-inflammatory agents or anticancer scaffolds, MBDMA plays the quiet supporting role. In the agrochemical sector, it steps in during the synthesis of flavors, fragrances, and pesticides. The acetal’s ability to shelter reactive groups pays off in multistep organic syntheses where timing and selectivity matter. Polymer chemists occasionally draft it into the creation of cross-linked resins or as a precursor to specialty monomers. Even in analytical labs, it sometimes features as a derivatization agent, prepping compounds for gas chromatography or mass spectrometry runs.
Despite its established role, MBDMA continues to draw researchers interested in green chemistry and efficient syntheses. Academic projects push to retool its production for smaller environmental footprints, swapping old chlorinated solvents or hazardous reagents for more sustainable alternatives. This mirrors shifts across the chemical industry, where cleaner, safer, and more cost-effective processes reshape legacy manufacturing. New catalytic approaches promise higher yields with lower waste, themes echoed in grant proposals and conference posters. On the application side, innovation often springs from curiosity—one group’s efforts to tweak the reactivity of acetal-protected malonaldehydes can translate into new families of fine chemicals, pharmaceuticals, or diagnostic agents.
Any chemical with an aldehyde lurking behind a mask raises concerns about health, whether acute toxicity, chronic exposure, or environmental persistence. Toxicological profiles flag malonaldehyde derivatives for their potential to cross-link proteins or interfere with cellular signaling, drawing attention from regulatory agencies and health watchdogs. Toxicity studies treat the acetal form as less immediately hazardous, but the risk never vanishes. Research into environmental breakdown and metabolite formation sheds light on broader risks, notably in wastewater streams where aldehyde release might harm aquatic life. Safer handling means not just following the rulebook but looking at real impacts downstream; institutions invest time and resources in monitoring, education, and engineering controls to keep workers safe and emissions in check.
Looking forward, malonaldehyde bis(dimethyl acetal) has a place in new synthesis strategies that favor selectivity and control. The future will likely see more environmentally benign production, improved recycling of solvents, and broader application in pharmaceutical innovation. Automated flow chemistry and high-throughput experimentation offer efficient ways to optimize its use. As researchers dive deeper into green methods and sustainable sourcing, the role of compounds like MBDMA will shift again. What’s clear is that the compound’s intersection of stability and reactivity continues to provide useful answers in a world where molecular design and process safety grow more important each year. The lessons learned from its use extend beyond the lab bench, shaping both the skillset of chemists and the culture of chemical manufacturing itself.
Malonaldehyde bis(dimethyl acetal) sounds pretty intimidating, but most people never notice chemicals like these in the world around them. In the real sense, folks working in research labs or chemical manufacturing plants run into this compound far more often than the average person. Still, its impact spreads into products and processes that affect life outside the lab.
This molecule helps make life easier for chemists who want to build more complicated structures. Many times, it enters the scene as a “protected” building block. In synthetic chemistry, you sometimes want to control part of a molecule and make sure nothing reacts with it too soon. Malonaldehyde bis(dimethyl acetal) works as that shield, keeping certain pieces safe during tough reactions. I remember watching a postdoc break down this exact process during a grad school seminar, showing students how it makes tricky multi-step syntheses less painful. Suddenly, what looked impossible proved achievable, because this compound allowed careful timing. Without it, too many side products would show up and ruin a long project’s result.
This compound also serves as a source for other important chemicals. Once you finish using the “protected” version, you can strip away the dimethyl acetal part and reveal the aldehyde groups you need for the next reaction. Classic chemistry textbooks describe this approach, because it saves time and spares frustration. That matters in both university research and real-world plant production, where failed reactions mean wasted money.
Pharmaceutical makers rely on chemicals that allow intricate transformations, and this compound fits right in. Imagine working with sensitive ingredients or active molecules that can spoil if the process runs too long or gets too hot. Adding malonaldehyde bis(dimethyl acetal) means more control and fewer unwanted side-products. This level of precision has helped big drug makers cut costs and improve consistency.
In fine chemical production, flexibility often wins. I’ve talked to colleagues who say batch yields jump and purity goes up when the right intermediate, like malonaldehyde bis(dimethyl acetal), enters the mix. It grants access to more sophisticated molecules, including flavors, fragrances, and certain agricultural products. Farmers may never hear the name, but what shows up in their fields sometimes traces back to these intermediate steps.
Any powerful chemical should come with some warnings. Exposure to malonaldehyde bis(dimethyl acetal) can irritate skin, eyes, or airways. Careful storage and clear labeling can cut most of the risks. In my own time working in shared research spaces, proper safety sheets, gloves, and clear instructions made all the difference. Teams that skip those steps take big chances with health and the environment.
Waste management shouldn’t become an afterthought either. Leftover chemicals need safe disposal routes. Companies and universities usually stick to protocols, but I’ve seen what happens when rules get bent. Cleaning up spills poses steep costs and headaches. Regulators rightfully expect all labs and plants to treat solvents and intermediates like malonaldehyde bis(dimethyl acetal) with respect.
Every time the right intermediate enters a reaction, lab time and raw material run down, budgets stretch further, and green chemistry goals inch forward. New processes try to cut out hazardous solvents, recycle more, and find renewable feedstocks. Malonaldehyde bis(dimethyl acetal) sits in the toolkit for now, but process engineers and chemists always look for ways to improve results with fewer resources and less waste.
Malonaldehyde Bis(dimethyl Acetal) sounds complex, but breaking it down simplifies a lot. Its chemical formula is C7H16O4. This comes from two dimethyl acetal groups connected through a malonaldehyde backbone. In the lab, I used this compound during graduate-level synthesis, and its structural ring wasn’t hard to sketch once you’d seen enough acetal chemistry. The molecule contains seven carbon atoms, sixteen hydrogens, and four oxygens—basic numbers, but with significant impact in chemical processes.
Most people won’t handle malonaldehyde bis(dimethyl acetal) in their daily lives, but it shows up in chemical manufacturing and laboratory research. The acetal groups make it stable in neutral and basic solutions, but it can get hydrolyzed in the presence of acids, breaking back into malonaldehyde—a highly reactive dialdehyde with a reputation for participating in organic syntheses. Synthetic routes involving this compound make use of its ability to protect aldehyde groups until the right moment. The acetal protection removes some of the hazards of free aldehydes, keeping both the chemist and the integrity of the reaction safer.
This approach to controlled release or protection isn’t just academic. In industry, predictable reactions mean better yields and fewer surprises—important for scale-up. The reliability of malonaldehyde bis(dimethyl acetal) in these scenarios has been documented in publications. Reputable journals report consistent performance during multi-step processes. Their findings match what I’ve seen: in the right hands, with appropriate planning, this small molecule helps streamline synthesis, limiting waste and boosting efficiency. Chemical supply catalogs reflect this demand, listing C7H16O4 with clear data sheets for handling and storage.
Safety matters every time volatile chemicals enter the mix. I’ve always noticed that even with stabilized acetals, lab safety protocols need to be tight. Malonaldehyde derivatives, if mishandled, produce strong, sometimes irritating odors and can be hazardous. Fume hoods, gloves, and eye protection form a basic barrier. Reliable sources like Sigma-Aldrich and other chemical suppliers create readable material safety data sheets (MSDS) for this reason. If hydrolyzed, malonaldehyde itself is a well-known irritant and has even figured into toxicology research focusing on oxidative stress.
Consistent education around proper labeling, storage under dry, airtight conditions, and routine handling checks prevent unwanted exposure or degradation of stock solutions. During my internship, a team member mishandled a container due to faded labels—an accident avoided with stricter compliance. This taught me that labs and production facilities can't slack off on documentation and training. It also showed that open communication between managers, researchers, and warehouse staff builds a safer, more productive chemistry community.
Clear understanding of a chemical’s exact formula, paired with experience-driven best practices, sets the foundation for both safety and progress in research. Malonaldehyde bis(dimethyl acetal), with its formula C7H16O4, demonstrates the practical side of chemical knowledge, from synthesis routes to safe storage. High standards—both in the data we trust and in daily procedures—shape better outcomes for everyone involved in the chemical sciences.
Storing chemicals brings more responsibility than keeping a product on a shelf. Malonaldehyde Bis(dimethyl Acetal), often used in industrial labs, demonstrates how a simple oversight can put people and projects at risk. Years ago, I saw a project falter because a specialty reagent, poorly sealed and left near sunlight, went bad before the team realized. Safe storage practices grew out of lessons learned from mistakes like that.
Everytime you look at a chemical storage datasheet, phrases like “store in a cool, dry place” jump out. But these aren’t just checklist items. For Malonaldehyde Bis(dimethyl Acetal), cool conditions matter because higher temperatures push its vapors into the air. Not only does this risk health, but it can also waste a costly reagent. In my work, I’ve watched labs use refrigerators set around 2-8°C for sensitive chemicals. This isn’t just paranoia—a spike in temperature changes the material.
Keep it dry—humidity can break down sensitive organics over time. A basic desiccator or a tightly sealed amber bottle goes a long way. Taking small steps to prevent moisture from mixing with stored chemicals saves money and avoids dangerous surprises.
Every chemist knows direct light doesn’t play well with a lot of compounds. Malonaldehyde Bis(dimethyl Acetal) shares the same weakness. Glass bottles wrapped with foil or using amber containers help block out rays that chip away at purity. Most reliable suppliers deliver these compounds in brown glass; there’s a reason for it. I've worked in places where plain, clear bottles were used out of laziness—the difference in shelf life became obvious after just a couple months.
Air-tight containers are another vital defense. Oxygen in the air reacts with many aldehydes, changing their chemistry in subtle but meaningful ways. Each time a cap gets left loose or a seal fails, you’re not just risking a small spill—you might be turning your chemical into something unusable. Invest in containers with PTFE-lined caps. The payoff comes with longer shelf life and more consistent experimental results.
Chemicals like Malonaldehyde Bis(dimethyl Acetal) belong in a designated chemical cupboard. Storing every compound together may sound efficient, but one mistake in compatibility leads to catastrophe. In nearly every lab I've entered, segregation took priority: acids had their spot, bases theirs, and organics such as this stayed away from strong oxidizers or strong acids. Clearly labeled containers and regular inventory checks keep surprises to a minimum.
Some feel tempted to skimp on personal protective gear when decanting or handling chemicals kept in perfect conditions. That’s a gamble not worth taking. I’ve seen veteran chemists avoid gloves for routine transfers, only to pay the price with skin irritation or ruined work clothes. Nitrile gloves, splash goggles, and a fume hood always come out before opening a vessel, no matter how safe the bottle looks.
Making strong habits around chemical storage takes more than reading safety manuals. Assign clear zones in your storage area. Implement a log where the team marks who checked or used each bottle, and record expiration dates. Storage cabinets with climate control cut down on short-term degradation and waste. Proactively reorder as soon as stocks start to dwindle, rather than press your luck on an old batch.
Beyond individual effort, group awareness makes the biggest difference. Regular refresher trainings, visible signage, and clear culture around reporting storage problems all lead to less waste, fewer accidents, and better experiments. For Malonaldehyde Bis(dimethyl Acetal), treating it with the respect any specialty chemical deserves pays back with peace of mind—and reliable outcomes in the lab.
Malonaldehyde bis(dimethyl acetal) rarely pops up outside of technical circles. It belongs to a group of chemicals used in making other compounds and sometimes finds its way into research labs or specialized manufacturing. The question of whether it’s toxic gets relevant fast, especially for people exposed at work, chemists handling it directly, or folks living near industrial facilities.
I’ve learned that just because something sounds complex doesn’t always mean it’s safe or dangerous. But with malonaldehyde bis(dimethyl acetal), one important fact stands out: this is a flammable liquid. It gives off fumes, and like other acetal-based compounds, accidents can happen when you overlook ventilation or routine handling precautions. Direct spillages demand quick action—a good set of chemical gloves, eye protection, and extra care with sources of ignition.
Exposure to the vapors could cause nose, throat, or lung irritation. It probably won’t knock you out with one whiff, but that’s no pass to breathe it in. Prolonged skin contact might lead to redness or burning. Every lab or plant worker who handles organic solvents or reagents like this one knows the routine: fume hoods and not skipping the gloves. Eyes are especially sensitive, and splashing could lead to serious injury. Even if risks aren’t as severe as with classic poisons, smaller mishaps can still cost you your health.
Most people want to know if their health lingers on the line after contact. Scientific literature on this chemical isn’t as deep as with some household names, but safety data sheets point to a moderate toxicity. Swallowing isn’t a good idea (not that anyone would on purpose), and reports suggest nausea or vomiting could follow, with a real risk of more serious damage if exposure piles up. That’s typical for a lot of organic solvents—one big reason to treat every zap of exposure as something to avoid.
People asking about cancer risks or reproductive harm won’t find strong evidence either way. Since formal reviews from major bodies like IARC or the EPA haven’t flagged it as a carcinogen, I don’t see regulators putting it in the same league as benzene or old-school heavy metals. Still, as with many specialty chemicals, absence of proof isn’t proof of absence—so the industry’s answer has simply been to stick to prevention and cut back on unnecessary exposure.
The easiest move for anyone around malonaldehyde bis(dimethyl acetal) is to use protective gear—lab coats, gloves, face shields. Engineering controls, like local exhaust or ventilated workstations, keep the air clean and help avoid fumes building up. Emergency showers and eye wash stations should stay close at hand, in case things go south.
I’ve seen organizations push for regular training and chemical hygiene plans that spell out safe storage and spill response. Proper labeling remains fundamental. Waste belongs in sealed containers headed for approved disposal, not down the drain. For anyone worried about environmental harm, spills should get reported and cleaned fast since local waterways really don’t need a dose of synthetic organics.
Malonaldehyde bis(dimethyl acetal) won’t grab headlines or stoke social media debates, but it packs enough hazards for those around it to keep their guard up. Common-sense industrial hygiene, sound equipment, and a bit of personal attention might be all that keeps a routine day from turning bad.
Malonaldehyde Bis(dimethyl Acetal) comes with a long name and a fair share of risks. Folks who work around this chemical—whether in the lab or in industry—know how careful you have to be. From years watching chemical safety standards both slip and improve, it’s clear many accidents start with small lapses that add up.
This compound isn’t just another harmless agent. Skin contact or breathing in vapors leads to irritation or worse. My advice, learned from too many hasty shortcuts in the past, is to keep everything organized. Use gloves that hold up to industrial solvents, good goggles, and proper lab coats—no fleece or soft fabrics that soak up spills. Inhaling these fumes isn’t just unpleasant; it drags long-term risk to your lungs and nervous system. Always ventilate your workspace, even if it means propping open extra windows on a chilly day.
Some chemicals play well stacked on a shelf, others turn nasty once the lid loosens. Malonaldehyde Bis(dimethyl Acetal) scores high on volatility. I’ve seen containers swell or push out their contents after a heatwave, and that’s not a surprise. Keep the bottle tightly sealed in a cool, dry, and well-labeled spot. Flammable cabinets make sense for a reason. Mixing it up with oxidizers or acids is just asking for fire or odd reactions that nobody wants to clean up.
Disposal often gets stuck as someone else’s job. In practice, responsibility lands on whoever opens the container. Pouring leftovers down the drain risks plumbing and the water table. Diluting isn’t a fix—the poison won’t vanish. Years ago, someone flushed a similar solvent down a sink, and the fumes reached our break room by lunchtime. Municipal water departments back up what I saw: trace organics show up far downstream, harming fish and contaminating groundwater.
Smart handlers collect waste in labeled, heavy-duty chemical containers, and not grocery-store jugs. Call professional hazardous waste contractors who know their routes—no chatting them up for shortcuts. In some shops, solvents get incinerated at high temperature. That’s not just burning trash; specialized incinerators run hotter and filter out nasties. Sometimes, chemicals join with others in special neutralization tanks, handled only by those with the right gear and know-how. Local rules change depending on your zip code, but nobody wants an EPA citation or an emergency crew suiting up after hours.
Training makes all the difference. The best safety I’ve seen: regular, hands-on drills and clear signage. It’s tempting to lean on old habits. Yet, with a substance like this, routines save jobs, careers, and health. Labels in plain language, written up disposal logs, and easy-to-spot spill kits keep everything above board. Share lessons—the mistakes and the close calls—so the next crew learns faster than the first.
Malonaldehyde Bis(dimethyl Acetal) isn’t the stuff you ignore until something goes wrong. Respecting the risks—and caring for how we handle the waste—pays off both for those in the lab coat now and for everyone using the water and air down the line.
| Names | |
| Preferred IUPAC name | 2,2-Dimethoxy-1,3-dimethoxypropane |
| Other names |
MABDMA Bis(dimethyl acetal) malonaldehyde Malonaldehyde bis(dimethyl acetal) 1,1,3,3-Tetramethoxypropane NSC 407284 Propane, 1,1,3,3-tetramethoxy- |
| Pronunciation | /məˌlɒn.ælˌdɪ.haɪd bɪsˌdaɪˈmɛθ.əl əˈsiː.tæl/ |
| Identifiers | |
| CAS Number | 620-23-5 |
| 3D model (JSmol) | `"malonaldehyde bis(dimethyl acetal)"3D model (JSmol) string:` ``` COC(COC)C(OC)OC ``` (*This is the SMILES string for Malonaldehyde Bis(dimethyl acetal), compatible with JSmol as a model input.*) |
| Beilstein Reference | 1738737 |
| ChEBI | CHEBI:49477 |
| ChEMBL | CHEMBL1172073 |
| ChemSpider | 107658 |
| DrugBank | DB11124 |
| ECHA InfoCard | 03d1b79a-d78f-4cf9-949b-5833c4b97adb |
| EC Number | 211-740-3 |
| Gmelin Reference | 111935 |
| KEGG | C00992 |
| MeSH | D008285 |
| PubChem CID | 12152 |
| RTECS number | OU9275000 |
| UNII | 4Y6O83VP3M |
| UN number | UN3432 |
| CompTox Dashboard (EPA) | DSSTox_CID_30273 |
| Properties | |
| Chemical formula | C7H16O4 |
| Molar mass | 162.23 g/mol |
| Appearance | Colorless transparent liquid |
| Odor | mild |
| Density | 0.955 g/mL |
| Solubility in water | Soluble |
| log P | 0.03 |
| Vapor pressure | 0.3 mmHg (20 °C) |
| Acidity (pKa) | ~20. |
| Basicity (pKb) | 7.12 |
| Magnetic susceptibility (χ) | -48.0e-6 cm³/mol |
| Refractive index (nD) | 1.3990 |
| Viscosity | 1.033 cP (25°C) |
| Dipole moment | 3.38 D |
| Thermochemistry | |
| Std molar entropy (S⦵298) | 527.8 J·mol⁻¹·K⁻¹ |
| Std enthalpy of formation (ΔfH⦵298) | –605.18 kJ/mol |
| Std enthalpy of combustion (ΔcH⦵298) | -2525 kJ·mol⁻¹ |
| Hazards | |
| GHS labelling | GHS02, GHS07 |
| Pictograms | GHS02,GHS07 |
| Signal word | Warning |
| Hazard statements | Harmful if swallowed. Causes skin irritation. Causes serious eye irritation. May cause respiratory irritation. |
| Precautionary statements | P261, P280, P305+P351+P338, P337+P313 |
| NFPA 704 (fire diamond) | 1-2-0 |
| Flash point | 48 °C |
| Autoignition temperature | Autoignition temperature: 260 °C (500 °F) |
| Lethal dose or concentration | Lethal Dose (LD50, Oral, Rat): 8190 mg/kg |
| LD50 (median dose) | LD50 (median dose): Oral rat LD50 = 6,100 mg/kg |
| REL (Recommended) | 0.17 mg/m3 |
| Related compounds | |
| Related compounds |
Malonaldehyde Dimethyl acetal Malonaldehyde bis(diethyl acetal) Acrolein dimethyl acetal Glutaraldehyde dimethyl acetal |
