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Lithium Bromide: More Than Just a Laboratory Staple

Historical Development: From Curiosity to Cornerstone

Lithium bromide didn’t just pop up as a star in chemistry labs overnight. Its story goes back to the age when chemists first started poking at the periodic table with serious intention. People learned that lithium, a soft, light metal, could team up with various halogens, and by the end of the 19th century, researchers got their hands on lithium bromide thanks to simple reactions. What started as an academic curiosity picked up steam once folks realized its knack for interacting with water and forming strong solutions. Before long, engineers and tinkerers began seeing possibilities beyond the test tube, and by the 20th century, lithium bromide had broken out of the lab, driving innovation in refrigeration and air conditioning. It became clear pretty early: some substances earn their place through sheer utility, and lithium bromide stepped up just as industries expanded and demanded more from basic chemistry.

Product Overview: Everyday Invisible Importance

For a lot of people, lithium bromide stays mostly behind the scenes. It doesn’t get the fame of lithium in batteries or the glow of bromine in old flame retardants, but it keeps running in the background. Commercial lithium bromide usually appears as a colorless, odorless powder or chunky solid—easy to overlook in a pile of other salts. Its value comes out most clearly in HVAC systems as an absorbent for industrial absorption chillers, where it keeps buildings cool without compressors. The substance excels at soaking up water vapor, which turns it into a key ingredient for places that need moisture removed or temperatures brought down without complicated machinery. It also pops up in organic synthesis, where chemists use its reactivity for creating new compounds. What’s funny is, so much quiet work depends on this simple compound, yet lithium bromide barely registers in the public eye.

Physical & Chemical Properties: Distinct and Consistent

Unlike many salts that clump up or react with air, lithium bromide stands up to moisture without caking outright, thanks to strong ionic bonds and moderate water affinity. It dissolves quickly, forming nearly clear solutions that reach impressive concentrations—qualities driving its adoption in refrigeration. Its melting point falls below 550°C and it boils at higher temperatures, but most of its practical uses stick to liquids rather than pushing it to those extremes. Chemically, it reacts easily with strong acids and bases, breaking apart or recombining but generally holding steady unless poked with stronger reactants. This steadiness appeals to people who build systems where chemical surprises cause big headaches. In solution, lithium bromide draws in water rapidly, which can cause containers to rust or corrode if not handled properly. This property explains its starring role in absorption chillers, where it works almost like a sponge for humidity.

Technical Specifications & Labeling: Clarity Over Complexity

If you ever pore over a lithium bromide drum, you’ll find technical information that leaves little room for guesswork: purity percentages, maximum concentrations, warning pictograms, and storage tips. These details matter, especially in HVAC or chemical manufacturing, where stray contaminants or tiny changes in water content can throw off an entire process. Labels steer clear of marketing fluff and zero in on numbers and control data, reflecting the substance’s no-nonsense job. This directness keeps engineers, chemists, and facility managers in sync, reducing the risk of accidents or costly downtime. Some lots get labeled with batch numbers and shelf-life because lithium bromide lives out its days in sensitive machinery and must avoid surprise breakdowns. While the average consumer probably never sees this information, every expert who works with this salt recognizes the value that precise specs bring to large-scale projects.

Preparation Method: Industrial-Scale Chemistry in Action

Making lithium bromide at scale looks straightforward on paper but requires attention to details that keep output clean and pure. Most production starts with lithium carbonate and hydrobromic acid—the latter providing bromide ions needed for the reaction. Once the acid and base meet, carbon dioxide bubbles off and leaves behind a lithium bromide solution, which gets concentrated by evaporation. The key challenge lies in maintaining clean reaction vessels and water supplies, as small traces of other ions can mess with the compound’s drying or forming steps. After evaporation, what remains gets dried further and often recrystallized to remove leftover impurities. In my experience, even a minor slip on water quality or temperature can force multiple extra purification steps. One careless batch can gum up delicate valves or cause corrosion in a high-stakes system, so trust and consistency in preparation become worth their weight in gold—sometimes literally, considering the cost of rework.

Chemical Reactions & Modifications: Versatile and Reliable

Simplicity in reactivity isn’t always a bad thing. Lithium bromide won’t jump at every available reactant, but it gets the job done where it counts. It can swap ions in solution, and you’ll often see it reacting with phosphates, sulfates, or even combining in more complex syntheses. For folks in organic chemistry, lithium bromide helps with certain protection and deprotection steps. In technical settings, some try to tweak lithium bromide solutions with additives to combat corrosion or boost absorption. Over time, researchers discovered the combinations that keep performance high and deterioration low. The salt’s relative lack of surprises means users can forecast results and avoid expensive failures. In refrigeration loops, for example, mixing just enough corrosion inhibitors prevents facility-wide emergencies. Work like this keeps older buildings and newer projects running smoothly where downtime costs far more than the price of a drum of chemicals.

Synonyms & Product Names: More Than One Label

Step into a storeroom or scroll through a chemistry supply catalog, and the same material often pops up under a handful of names: LiBr, lithium monobromide, or more plainly, lithium bromide. Each label carries weight depending on context—LiBr turns up in academic papers and lab protocols, while “lithium bromide solution” gets stamped across tanks at large-scale facilities. Whether you’re looking at ancient handbooks or the latest research journals, these synonyms chase the same product, reminding users that underneath the branding and shorthand, the chemistry remains constant. The details might vary by manufacturer, but the need for clear, unmistakable identification continues as systems grow more complex.

Safety & Operational Standards: Risk Managed, Not Ignored

In my own hands-on experience, it’s hard to overstate the value of strict safety procedures with lithium bromide. While it doesn’t react violently with air or spark major chemical fires, it does have downsides that demand real respect. Direct contact dries out skin or causes mild irritation, but things get uglier if lithium bromide enters the eyes or gets swallowed. Serious exposure, including inhalation of dust, brings health risks you don’t want to deal with: headache, stomach upset, confusion. That means gloves, eye protection, and good ventilation aren’t just best practices—they’re non-negotiable. Standard workplace rules call for spill kits, emergency eyewash stations, and detailed training on what to do when things go wrong. In tight spaces, regular checks for leaks and corrosion keep people safe and equipment running. Even though the dangers don’t always reach the level of other industrial hazards, ignoring them invites trouble, especially where large volumes flow through pipes and tanks daily.

Application Areas: Cooling, Synthesis, and Beyond

For urban office towers or sprawling hospitals, lithium bromide keeps things comfortable through summer scorchers and winter setbacks. Cooler water runs through chillers using this salt as an absorbent, removing heat from inside walls without relying on old-school compressors. Unlike traditional air conditioners that gobble up electricity, absorption chillers work quietly and sometimes use waste heat, making them a favorite for smart-building engineers. In synthetic chemistry, lithium bromide plays a subtler yet crucial role in forming certain catalyst complexes or splitting apart organic compounds. Pharmaceutical researchers also turn to LiBr when they need a predictable, reactive partner during synthesis steps. Outside of the obvious, some folk probe its use in specialized batteries or advanced desalination technologies—fields where reliability and chemical predictability still matter. No matter where it lands, lithium bromide proves itself by solving real-world problems, not just showing up as a line item in a supplier’s catalog.

Research & Development: Curiosity Driving Progress

Nobody seems content resting on yesterday’s discoveries, and lithium bromide finds itself drawn into the future by innovators hunting for more out of less. Early absorption chillers set the scene, but now researchers dive into combining lithium bromide solutions with new corrosion inhibitors, or coupling it with smart heat pumps designed to slash carbon footprints. Over in the lab, synthetic chemists probe how LiBr speeds up certain steps, aiming for cleaner reactions or fewer byproducts. Recent years brought fresh takes on using lithium bromide in batteries, where its stable, ionic nature makes it a candidate electrolyte for experimental designs. Every step forward, no matter how small, opens options for industries hunting new efficiencies. What’s encouraging is seeing so many voices—chemists, process engineers, environmental researchers—all pushing in different directions, but tethered together by the same basic compound. Real progress takes time, and lithium bromide, with its steady, predictable behavior, gives people space to try new things without fearing unpredictable chemical meltdowns.

Toxicity Research: Facing Real Risks Without Panic

Facts matter most when dealing with toxicity. Unlike some other chemicals crowding industrial stockrooms, lithium bromide doesn’t hide big, dramatic risks, but it also doesn’t earn a free pass. Getting too much into the human system disrupts nerve and kidney functions, causing symptoms that range from mild to potentially serious. Workers handling this stuff rely on strict rules: never eat or drink near open containers, clean up with care, and avoid letting any solution linger on the skin. Research so far suggests that, with normal workplace hygiene, dangers stay low, but long exposures or big spills can lead to trouble. Science keeps pushing to understand long-term risks, asking how exposure adds up over years, especially for workers clocking decades around this chemical. Some regulatory bodies set workplace limits, and responsible companies keep measurements below those thresholds. Safety depends on real knowledge, not guesswork or false assurances—a lesson learned through decades of both good and bad experiences.

Future Prospects: Opportunities, Questions, Challenges

Lithium bromide stands to gain as the world leans harder into renewable energy and tries to cut the tangle of greenhouse gas emissions. Absorption cooling ticks many boxes for efficient, electricity-light building management, and as clean energy costs drop, interest in plugging in low-waste cooling shoots up. Technology improvements target longer-lasting, easier-to-maintain LiBr-based chillers, and new additives seek to bank even more performance for the same input. Beyond that, the battery community looks for stable, safe ways to store charge, asking whether lithium bromide can take lessons from the past and build better cells for tomorrow’s devices or grid storage. Environmental scientists press for better stewardship over how the salt gets made, used, and disposed of, challenging industry to shrink waste streams and avoid triggering broader problems. The future for lithium bromide isn’t set in stone—the stuff’s chemistry remains steady, but what people do with it keeps the story moving. The push for efficiency, safety, and sustainability leaves a big opening for this once-obscure salt to keep proving its worth in new and surprising ways.




What is Lithium Bromide used for?

How Lithium Bromide Shapes Daily Life

Every day, millions of people walk into chilly lobbies, cool offices, or hospitals with cool, dry air and feel a quick sense of relief. Most never stop to think about the technology working behind the scenes. Lithium bromide, a clear salt that dissolves easily in water, quietly powers many of these air conditioning systems. Its use isn’t loud or flashy, but it’s deeply important—especially in countries where humidity sits heavy in the air for much of the year.

A Salty Solution to an Ancient Problem

Water vapor is a persistent problem for buildings and machines. Too much humidity brings more than discomfort—it leads to fungus, corrosion, and can even mess with electronics. Lithium bromide comes into play mainly in absorption chillers: machines that help keep buildings cool by removing heat and moisture. Instead of using toxic or flammable gases like those found in some older refrigeration systems, these chillers use lithium bromide mixed with water. The salt attracts and absorbs water vapor, drawing it out of the air so the cooling process runs efficiently.

Health Care Can't Ignore Lithium Bromide

Hospitals depend on strict temperature control to keep medicines stable, protect sensitive equipment, and provide comfort to patients. Lithium bromide chillers often do this job quietly. The cooling action doesn’t just make things comfortable; it helps cut risks from heat stress, especially for vulnerable patients. I know this first-hand, having volunteered at a clinic in a rural area where a broken air system—one not using the robust absorption process—once spoiled an entire supply of vaccines.

Industry Leans Heavily on Absorption Chillers

Factories that process food, produce textiles, or store medicines all benefit. By lowering their dependence on electricity and using water as the “working fluid,” lithium bromide chillers help cut energy bills. They often run on waste heat, which turns what used to be an environmental headache into a source of efficiency. The result? Lower energy costs and less pressure on power grids.

Drawbacks and Cautions

Lithium bromide isn’t without downside. Strong solutions of the salt can damage equipment if leaks go unchecked. Corrosion eats away at chiller parts and leads to expensive downtime. Strict maintenance and inhibitors can buy more time for equipment, but cutting corners brings real risks. Safety guidelines from groups like the American Society of Heating, Refrigerating and Air-Conditioning Engineers (ASHRAE) stress the need for regular checks and safe handling.

What Could Make the Future Brighter?

Better materials for chiller components, new corrosion inhibitors, and real-time sensors for monitoring lithium bromide levels offer hope for longer-lived, safer machines. Research teams are searching for alternatives that keep the performance but reduce health and environmental concerns. For the moment, though, lithium bromide keeps winning out because it does its job so well.

The Bigger Picture

Lithium bromide’s story underscores how chemistry sits at the heart of much modern progress—even if you rarely hear its name. As the climate heats up and energy demand rises, old problems like humidity don’t disappear. They force us to rethink the technology behind comfortable spaces—and to appreciate the unglamorous but essential ingredients working out of sight.

Is Lithium Bromide hazardous or toxic?

Risk and Reputation: The Truth Behind Lithium Bromide

Lithium bromide seems to fly under the radar for most people unless you’ve worked in HVAC or chemical labs. You’ll find it running chillers and refrigeration systems, where it keeps things cool without the fuss of more volatile chemicals. Even so, safety concerns keep cropping up, especially after stories of workplace exposure or accidental spills.

This chemical doesn’t act like your typical strong acid or base. At room temperature, lithium bromide usually looks like a white, flaky solid or a clear, syrupy solution. Its danger doesn’t come from explosions or noxious fumes, but it still finds ways to cause trouble. Getting lithium bromide on your skin leaves a burning, itching feeling if you don’t wash it off pretty fast. In my lab days, I learned to spot its oily texture from across the bench, reaching for gloves and goggles before even grabbing the bottle.

Handling and Health Risks

The real hazard comes from ingestion and inhalation. Lithium bromide isn’t the kind of substance you want near your food or mouth. Swallowing it means possible nausea, vomiting, or, in larger doses, tremors and confusion. Inhaling the dust or mist won't blow you over, but after hours of breathing it in, workers can end up with a sore throat, cough, or even more serious lung symptoms. OSHA and NIOSH have weighed in, recommending limits for air exposure and a full suite of PPE for workers in the industry.

Chronic exposure doesn’t get nearly as much press as it deserves. Extended contact can lead to symptoms like weight loss, headache, and even thyroid dysfunction. The lithium inside the formula can disrupt the body’s salt balance. Bromide follows up with its own issues, including drowsiness and skin rashes if levels build up. I’ve seen folks in old chemical plants talk about “bromism,” a strange sluggishness and tremor. Turns out, that’s not just folklore but a real occupational risk.

Environmental Concerns

Most lithium bromide spills don’t trigger environmental nightmares the way oil or mercury do. But this stuff seeps into water, breaks down slowly, and can harm aquatic life. Not every spill makes headlines, but the truth is, fish and amphibians have trouble adapting to elevated lithium and bromide ions. Even if the immediate footprint stays small, repeated leaks pile up over time.

Workplace Realities and Practical Prevention

Daily safety around lithium bromide boils down to good habits. I’ve watched too many coworkers skip gloves because they’re in a hurry, only to end up with red, irritated skin. Chemical-resistant gloves, eye protection, and proper ventilation cut down most of the risk. Showers and eyewash stations remain non-negotiable in any facility that uses this chemical. Storage matters too: it reacts badly with water, acids, and oxidizers, so locking it up tight keeps problems at bay.

Lab managers and safety trainers ought to move beyond reciting rules and focus on real engagement with workers. Explaining the “why” behind every protocol makes a bigger impact than a poster stuffed in the breakroom. Regular health screenings spot creeping symptoms before they turn serious, and spill response drills drill the message home that safety is a shared job.

Moving Forward

There’s no single answer to making lithium bromide completely safe. Tighter exposure limits and better monitoring would help. Manufacturers exploring safer alternatives for chillers and air conditioners could cut down on risk, but right now, demand remains strong for robust, water-based absorption systems. For now, a strong commitment to worker education, prompt spill response, and rigorous protective protocols offers the best line of defense. Real-world experience and a healthy respect for the risks keep the workplace safer—and that’s what everyone deserves.

What is the chemical formula of Lithium Bromide?

Practical Chemistry in Everyday Life

Science class might seem distant until you realize those chemical names connect with technology and comfort all around us. Lithium bromide, for instance, isn’t just a collection of syllables from a test. It works behind the scenes, especially in air conditioning and refrigeration, offering direct benefits to indoor comfort that everyone can feel. To understand why it matters, start with the basics: the chemical formula is LiBr. Simple, but behind that formula sits a ton of real-world utility.

Breaking Down LiBr

It's not just about knowing letters and numbers; understanding why lithium and bromide stick together offers clues about how science gets applied. Lithium, lightweight and highly reactive, links easily to bromine, a heavier, highly reactive halogen. They form an ionic bond, and that bond provides stability in ways that pure elements don’t. The resulting compound dissolves easily in water, which is part of why it lands in absorption chillers—machines that create cooling without the typical compressor. Instead, lithium bromide’s ability to soak up water vapor helps move heat in a quiet, energy-efficient way.

Real-World Connection and Value

Well over a century ago, researchers discovered combinations like LiBr could help drive technologies that need efficiency and reliability. In residential cooling systems, it absorbs moisture to dehumidify the air, creating a noticeable difference in muggy climates. Anyone who’s stepped into a cool, dry building on a humid day already understands the value—no chemistry degree required.

The reliability of lithium bromide’s chemistry holds up even as needs evolve. Energy use keeps rising, stressed by growing populations and bigger cities. Solutions like absorption chillers using LiBr lower electricity demands. These systems often rely on waste heat or renewable sources instead of fossil fuel electricity. If you work in building management, this matters for the bottom line. If you’re concerned about emissions and climate, the impact gets even bigger.

Challenges and Opportunities

Lithium bromide does come with some headaches. It’s hygroscopic, meaning it pulls in water from the air. Systems have to be airtight, because leaks don’t just waste money—they risk damage to equipment. Plus, using lithium on an industrial scale puts pressure on natural reserves, a problem made clearer as electric cars and renewable energy technologies boost global demand. Growth in green tech ties up major amounts of lithium for batteries, putting supply under a magnifying glass.

Tackling these challenges calls for better system design, strong maintenance routines, and ongoing innovation. Improving recycling could help lessen demand for freshly mined lithium. There’s steady progress in system efficiency, so less lithium bromide can do more with fewer leaks and breakdowns. In the bigger picture, research into alternative compounds may inspire new solutions—but what matters today is minimizing waste and maximizing the performance of current technology.

Looking Forward

Lithium bromide’s chemical formula, LiBr, stands as a bridge from textbook chemistry to the world’s efforts to cool, conserve, and innovate. Understanding it goes beyond academic interest; it links comfort, energy use, and resource conservation. Paying attention to how materials like LiBr shape daily experiences and public policy reminds us that science never stays locked in the lab. It keeps finding ways to solve immediate problems and shape tomorrow’s choices.

How should Lithium Bromide be stored?

Understanding Lithium Bromide’s Nature

Anyone who’s worked with Lithium Bromide knows its power and risk. This isn’t a chemical that tolerates carelessness. It draws water from air fast—leaving sticky, corrosive messes if you leave a jar open during humid weather. Dripping condensate from a poorly sealed barrel has ruined plenty of concrete floors and metal shelving. It can burn skin and eyes. Honest confession: early in my lab days, I ignored a cracked lid. By morning, half the tub turned into a slushy puddle, eating up the shelf liner. I’ve learned: keep it sealed, keep it dry.

Best Practices Rooted in Experience

Direct sunlight or warm conditions lead to pressure build-up and leakage, which means you’ll want to keep Lithium Bromide somewhere cool and shaded. A dry storage room helps avoid the constant fight with humidity. Thick, screw-cap bottles—preferably made from polyethylene or glass—work best. The chemical chews through thin plastics with time. Metal lids corrode fast, leaving flakes that end up in the solution.

Don’t put it high where staff might grab a container off a shelf above shoulder height. I’ve seen what happens when the jar slips: broken glass, caustic splash, liability. Keep storage low and stable, maybe in a locked cabinet if kids or untrained workers pass by.

Why Organization Matters

The Chemical Safety Board reports dozens of accidents from cross-contamination. It takes just one open bag of organic powder nearby for Lithium Bromide to start mixing, especially if someone’s poured a bit carelessly. Rows labeled in bold print cut confusion. It helps to keep the oxidizers, acids, and reactive metals in separate zones. Supervisors who build clear diagrams of chemical shelving rarely field emergency calls.

If there’s any sign of spill, mop up with sand or commercial absorbent right away. Don’t wash it down a regular drain. Local rules usually ask for hazardous waste bins and a record of what's tossed out each month. A small business caught flushing toxic salts faces heavy fines and public shaming.

Health Precautions Can’t Be Shortchanged

Years of chemical work can make “just this once” sound tempting, especially late in the day. No gloves, no eye shield, just a quick scoop to keep things moving. One splash in the eye changes the routine—pain, blurred vision, hospital trips. Protective goggles and nitrile gloves make the difference between a smooth shift and a medical report.

Emergency showers should stay uncluttered and in working order. I check the eyewash station myself each week. Safety gear feels like a hassle until you need it, then there’s no substitute.

Looking Toward Safer Storage Solutions

Manufacturers could make things easier by offering smaller, batch-sized drums with tougher tamper-proof seals. I’ve advocated for color-coded labeling that’s readable from meters away, not just fine print on a sticker. Real improvement happens where people trust each other to speak up about storage risks and maintenance. Letting everyone know where to find up-to-date safety data sheets creates a culture where the chance of disaster drops sharply.

After years of trial, error, and lessons learned, one thing proves consistent: Preparation and order outpace improvisation every time. Better storage habits and workplace honesty bring peace of mind—far more valuable than rushing through another chemical delivery day.

What are the safety precautions when handling Lithium Bromide?

The Real Risks of Lithium Bromide

Lithium bromide shows up in a lot of refrigeration and absorption systems, especially where chillers run nonstop. Anyone who’s handled this chemical before knows it’s got its own playbook of hazards. Contact with the skin can get painful fast: burning, itching, even blistering if someone’s unlucky or slow with the safety shower. Breathing in dust or fumes leads to coughing, sore throat, and sometimes more serious lung problems. Swallowed accidentally, it works no miracles for the stomach—nausea, vomiting, and sometimes even neurological issues hit hard.

Personal Protective Gear Isn’t Optional

Working with lithium bromide at the tank or in the lab isn’t a time to skimp on gear. I’ve seen more than one rookie jump straight in with bare hands and regret it. Nitrile gloves act as a must-have barrier. Safety goggles protect eyes from accidental splashes or dust clouds. A lab coat or long sleeves spare lots of misery if the solution goes flying. In areas with little air movement, a face mask helps fend off dust.

Handling Spills and Accidents the Right Way

Spills happen to everyone sooner or later. Tossing paper towels at a spill doesn’t cut it with lithium bromide. Dry powder can fly up with the slightest breeze, so working slow and steady works best. Sweeping up with a dustpan, using a disposable mask, and bagging waste for hazardous materials collection makes cleanup safer. If lithium bromide hits clothing, stripping off the garment and rinsing affected skin right away saves a trip to the clinic.

Good Ventilation Saves More Than Comfort

Hot, still rooms make the hazards of lithium bromide worse. If I walk into a mechanical room that smells sharp or makes my eyes sting, I open a window before doing anything else. Airflow reduces risk by clearing away dust, mist, or vapor before it gets into lungs or eyes. Local exhaust ventilation close to workstations keeps air safer where workers stand. If the system offers the choice, always go with it.

Storage That Reduces Surprises

Lithium bromide pulls water right out of the air. A leaky container means crusty lumps, slick puddles, and rust-stained shelves. Tightly closing every cap matters, and keeping everything in a cool, dry space with good labeling prevents accidents. Planning ahead to separate storage away from acids, oxidizers, and flammable solvents limits the risk of runaway chemical reactions. Long storage rarely improves things; only ordering enough for the job at hand avoids trouble.

Training Makes a Difference

Every crew member deserves straight talk about what lithium bromide can do. Safety meetings pay off, especially with veterans sharing stories and tips with new hands. Signs and charts stuck to lab doors make emergency steps easy to memorize. Simple drills teach everybody what to reach for in an emergency. Trained teams with real experience handle lithium bromide without drama, which keeps productivity up and people healthy.

The Value of Reliable Information and Practice

The safety data sheet for lithium bromide stays more useful than any rumor. I keep one posted near every storage area, so nobody needs to guess during a spill or exposure scare. Keeping the emergency contact numbers for poison control or workplace medics taped to the wall cuts the confusion if someone gets exposed. Anyone who’s ever needed fast medical advice after a spill appreciates not fishing for information in a panic.

Solutions That Stick

Engineering controls always help—closed handling systems and spill containment save clean-up time and lower risk. Written work procedures, regular training, and a steady supply of clean gloves and goggles make a huge long-term difference. Sharing real-world lessons—not just the theory—turns safety guidelines into reliable routines people actually follow. That’s where real protection against lithium bromide’s hazards begins.

Lithium Bromide
Names
Preferred IUPAC name lithium bromide
Other names Lithium monobromide
Lithium(I) bromide
Pronunciation /ˈlɪθiəm brəˈmaɪd/
Identifiers
CAS Number 7550-35-8
Beilstein Reference 358754
ChEBI CHEBI:63315
ChEMBL CHEMBL1200301
ChemSpider 50408
DrugBank DB14565
ECHA InfoCard 03d07075-bbe7-4b3f-94c2-9e8cad48dfb4
EC Number 200-143-0
Gmelin Reference Gmelin Reference: **14043**
KEGG C14326
MeSH D008089
PubChem CID 23665760
RTECS number OL3675000
UNII 9FN79X2M3F
UN number UN3095
Properties
Chemical formula LiBr
Molar mass 86.845 g/mol
Appearance White to yellowish solid
Odor odorless
Density 3.46 g/cm³
Solubility in water 166 g/100 mL (20 °C)
log P -3.18
Vapor pressure Vapor pressure: <0.1 hPa (20 °C)
Acidity (pKa) -1.8
Basicity (pKb) -0.17
Magnetic susceptibility (χ) −72.0×10⁻⁶ cm³/mol
Refractive index (nD) 1.784
Viscosity 1.92 cP (at 25°C, 50% solution)
Dipole moment 0 D
Thermochemistry
Std molar entropy (S⦵298) Sm°(LiBr, s, 298 K) = 57.1 J·mol⁻¹·K⁻¹
Std enthalpy of formation (ΔfH⦵298) -351.2 kJ/mol
Std enthalpy of combustion (ΔcH⦵298) -598.6 kJ/mol
Pharmacology
ATC code N05AN01
Hazards
Main hazards Corrosive, causes burns to skin and eyes, harmful if swallowed or inhaled, may cause irritation to respiratory tract.
GHS labelling GHS02, GHS07
Pictograms GHS05,GHS07
Signal word Warning
Hazard statements H302: Harmful if swallowed.
Precautionary statements P280: Wear protective gloves/protective clothing/eye protection/face protection.
NFPA 704 (fire diamond) 1-0-2-W
Lethal dose or concentration LD50 (oral, rat): 1180 mg/kg
LD50 (median dose) LB50 (median dose): Oral-rat LD50: 1180 mg/kg
NIOSH NL4025000
REL (Recommended) 24-7
Related compounds
Related compounds Lithium chloride
Potassium bromide
Sodium bromide