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Material Safety Data Sheet: Lead (II) Chloride

Identification

Product Name: Lead (II) Chloride
Chemical Formula: PbCl2
Synonyms: Plumbous chloride, Lead dichloride
CAS Number: 7758-95-4
Recommended Use: Academic research, laboratory reagent, chemical manufacturing
Supplier Contact: Chemical supplier information, emergency phone number available on request
Emergency Overview: White crystalline powder, toxic if ingested or inhaled
UN Number: 2291
EC Number: 231-845-5

Hazard Identification

GHS Classification: Acute toxicity (oral, inhalation, dermal), Harmful to aquatic life with long-lasting effects, Carcinogenicity, Reproductive toxicity
Signal Word: Danger
Hazard Statements: Toxic if swallowed or inhaled, suspected of causing cancer, may damage fertility or the unborn child, causes damage to organs through prolonged or repeated exposure, very toxic to aquatic life
Pictograms: Skull and crossbones, Health hazard, Environment
Precautionary Statements: Wear protective gloves/protective clothing/eye protection/face protection. Do not eat, drink or smoke when using. Avoid breathing dust/fume.
Target Organs: Kidneys, central nervous system, reproductive organs
Routes of Exposure: Inhalation, ingestion, skin, and eye contact
Physical Hazards: Non-combustible, but gives off toxic fumes in fire conditions.

Composition / Information on Ingredients

Chemical Identity: Lead (II) Chloride
Common Name: Lead chloride
CAS Number: 7758-95-4
Concentration: 99-100%
Impurities: Trace amounts of other lead compounds or metallic lead as process byproducts
Molecular Weight: 278.1 g/mol

First Aid Measures

Inhalation: Remove the exposed person to fresh air, keep at rest. If not breathing, provide artificial respiration. Seek medical attention immediately.
Skin Contact: Remove contaminated clothing. Wash skin thoroughly with soap and water. Medical treatment required if irritation or symptoms persist.
Eye Contact: Rinse immediately with plenty of water for at least 15 minutes, lifting eyelids. Obtain medical attention promptly.
Ingestion: Rinse mouth. Do not induce vomiting. Seek medical advice without delay. If unconscious, do not give anything by mouth.
Most Important Symptoms: Abdominal pain, headache, nausea, vomiting, confusion, anemia, neurological symptoms.
Indication of Immediate Medical Attention: If exposed or concerned, medical evaluation is necessary for chelation therapy and symptomatic management.

Fire-Fighting Measures

Extinguishing Media: Use dry chemical, foam, or carbon dioxide. Do not use water jets directly.
Hazardous Combustion Products: Emits toxic fumes of chlorine and lead oxides in fire situations.
Specific Hazards: Material is toxic; runoff from firefighting may pollute waterways. Protect against inhaling gases.
Special Protective Equipment: Wear full protective gear and self-contained breathing apparatus; avoid skin and eye contact.
Advice for Firefighters: Isolate the area and evacuate all non-emergency personnel. Prevent entry of water stream into sewers and waterways.

Accidental Release Measures

Personal Precautions: Evacuate unnecessary personnel. Isolate area and ventilate well. Wear suitable respiratory protection, gloves, and chemical-resistant clothing for cleanup.
Environmental Precautions: Prevent further leakage or spillage. Block entry to sewers, surface water, or soil.
Containment and Cleaning: Scoop or vacuum up spilled material. Avoid dust generation. Place in labeled chemical waste containers for disposal.
Decontamination: Wash contaminated surfaces and clothing with soap and water. Ensure all equipment used is thoroughly cleaned.
Notification: Report significant releases to environmental protection authorities as required by regulations.

Handling and Storage

Handling: Handle in a well-ventilated place. Avoid direct contact with skin, eyes, and clothing. Use closed systems if possible to minimize dust.
Hygiene Measures: Do not eat, drink, or smoke in areas where chemical is handled. Wash hands before breaks and after work.
Storage Requirements: Store in a tightly sealed container, kept in a cool, dry, ventilated place away from acids, bases, and foodstuffs.
Incompatible Materials: Avoid storage with ammonium salts, strong oxidizers, strong acids, and alkalis.
Segregation: Keep separate from explosive or easily oxidizable materials to reduce risk of hazardous chemical reactions.

Exposure Controls and Personal Protection

Exposure Limits: OSHA PEL: 0.05 mg/m3 (as Pb); ACGIH TLV: 0.05 mg/m3 (as Pb)
Engineering Controls: Use local exhaust ventilation or fume hoods to control airborne dust
Personal Protective Equipment: Protective gloves, chemical-resistant clothing, safety goggles, face shield
Respiratory Protection: Approved respirators required in absence of adequate ventilation or high exposure risk
Environmental Controls: Equipment should be used only in well-ventilated areas or with fume extraction. Prevent accidental emission into the environment.
Hand Protection: Impermeable gloves recommended
Eye Protection: Chemical safety goggles with side shields required
Skin Protection: Wear lab coats or suits, closed shoes, and have emergency shower facilities nearby.

Physical and Chemical Properties

Appearance: White crystalline solid or powder
Odor: Odorless
pH: 5.5-6.5 (20°C, saturated solution)
Melting Point: 501°C
Boiling Point: 950°C (decomposes)
Solubility in Water: 1.2 g/L at 20°C, slightly soluble
Vapor Pressure: Negligible at ambient conditions
Density: 5.85 g/cm3 at 20°C
Molecular Formula: PbCl2
Partition Coefficient (n-octanol/water): Not applicable
Flash Point: Not flammable
Evaporation Rate: Not applicable

Stability and Reactivity

Chemical Stability: Stable under recommended storage and usage conditions. Absorbs moisture from the air.
Reactive Hazards: May react with strong acids, bases, and ammonium salts releasing toxic fumes.
Decomposition Products: May release lead oxides and chlorine gases at high temperatures.
Polymerization: Will not occur.
Conditions to Avoid: Excessive heat, damp or humid conditions, incompatible materials.
Incompatible Materials: Strong oxidizers, acids, alkalis, and ammonium compounds.

Toxicological Information

Acute Toxicity: Oral LD50: 1940 mg/kg (rat)
Chronic Toxicity: Lead compounds may cause neurological impairment and organ damage with repeated or prolonged exposure.
Carcinogenicity: IARC: Group 2A (probably carcinogenic to humans). NTP: Reasonably anticipated to be human carcinogen.
Routes of Exposure: Inhalation, ingestion, dermal contact
Symptoms of Exposure: Abdominal pain, vomiting, headache, anemia, fatigue, tremors, memory loss
Reproductive Toxicity: Evidence of adverse developmental and fertility effects in humans and animals.
Other Effects: Peripheral neuropathy, kidney damage, hypertension, learning deficits (noted especially in children).

Ecological Information

Aquatic Toxicity: Highly toxic to aquatic organisms. May cause long-term adverse effects in aquatic environments.
Persistence and Degradability: Lead chloride does not degrade in natural environments. Tends to accumulate and persist.
Bioaccumulative Potential: Significant accumulation in plants and animals possible, especially from contaminated water bodies.
Mobility in Soil: Moderately mobile, especially in acidic conditions; may leach and contaminate groundwater.
Other Ecological Effects: Harmful impact observed in aquatic food chains and wildlife; risks increase in poorly controlled waste disposal.

Disposal Considerations

Waste Disposal: Treat as hazardous waste. Dispose of according to local, regional, and national regulations.
Packaging Disposal: Decontaminate or incinerate packaging in permitted facilities.
Do Not: Release product into drains, natural waterways, or soil.
Recommended Treatment: Chemical or stabilized landfill under strict environmental controls.
Contaminated Materials: Dispose of protective equipment and cleanup materials as hazardous waste.
Regulatory Considerations: Comply with federal and state guidelines for lead compounds in all disposal operations.

Transport Information

UN Number: 2291
Proper Shipping Name: Lead Compounds, soluble, n.o.s. (Lead (II) chloride)
Transport Hazard Class: 6.1 (Toxic Substances)
Packing Group: III
Label Required: Toxic
Marine Pollutant: Yes
Hazard Symbol: Skull and crossbones
Special Precautions: Transport only in original, secure, labeled containers; protect from spillage and mechanical shock.
Transport Regulations: Comply with international, national, and local transport laws including IMDG and IATA.

Regulatory Information

Regulation by Region: TSCA (listed); SARA Title III Section 313 (subject to reporting); CERCLA (reportable quantity 10 lbs for lead compounds); OSHA (hazardous standard); California Proposition 65 (listed - cancer and reproductive risk)
International Listings: Listed on EINECS, DSL, AICS
Worker Protection Requirements: Follow OSHA, NIOSH, and relevant health and safety standards for lead exposure.
Environmental Release Criteria: Facilities handling must comply with EPA reporting for accidental release.
Labelling: Product and packaging must display hazard and precautionary statements.
Restrictions: Sale, distribution, and use may be limited by regional or national bans on certain applications due to toxicity and environmental impact.