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MSDS for L-Tartaric Acid

Identification

Product Name: L-Tartaric Acid
Chemical Formula: C4H6O6
Synonyms: 2,3-dihydroxybutanedioic acid, L-(+)-Tartaric acid, Natural tartaric acid
CAS Number: 87-69-4
Recommended Use: Acidity regulator in food, pharmaceutical intermediate, laboratory reagent
Supplier Details: Manufacturer or distributor address and emergency contact information should be checked on the product label and technical datasheet at the point of purchase
Emergency Phone: Emergency contact numbers are found on the container or safety instructions materials for your specific product shipment

Hazard Identification

GHS Classification: Eye irritation Category 2A, Skin irritation Category 2
Signal Word: Warning
Hazard Statements: Causes serious eye irritation, causes skin irritation
Pictograms: Exclamation mark symbol
Precautionary Statements: Wear protective gloves and eye protection, wash hands thoroughly after handling, avoid inhaling dust
Physical Hazards: Not flammable, not explosive under normal conditions
Health Hazards: Direct contact may lead to redness or discomfort on skin and eyes, dust may irritate the respiratory tract

Composition / Information on Ingredients

Chemical Name: L-Tartaric Acid
Concentration: Typically >99% pure
CAS Number: 87-69-4
Impurities: Trace inorganic salts or water content below 1% in typical food- or reagent-grade product
Other Components: No hazardous stabilizers or additives usually present

First Aid Measures

General Advice: Remove contaminated clothing, seek medical attention if symptoms persist
Eye Contact: Rinse cautiously with water for several minutes, lift eyelids to ensure thorough flushing, consult an eye specialist if irritation continues
Skin Contact: Wash with mild soap and plenty of water, consult a doctor if rash or discomfort arises
Inhalation: Move person to fresh air, keep at rest, contact healthcare provider if feeling unwell
Ingestion: Rinse mouth thoroughly with water, drink water if conscious, do not provoke vomiting, seek medical attention if symptoms appear
Main Symptoms: Redness, pain or irritation of affected area, coughing or mild respiratory discomfort from inhaling dust

Fire-Fighting Measures

Suitable Extinguishing Media: Dry chemical, CO2, foam, or water spray
Unsuitable Media: Avoid high-pressure water streams that might spread dust
Special Hazards: At high temperatures, decomposition may produce carbon oxides, avoid inhaling smoke
Firefighting Instructions: Evacuate area, use self-contained breathing apparatus if exposed to decomposition products, maintain a safe distance
Protective Equipment: Full protective clothing and respiratory equipment for firefighters

Accidental Release Measures

Personal Protection: Avoid breathing powder, don protective gloves and eye protection, minimize skin contact
Environmental Precautions: Avoid runoff into drains or waterways, contain spill to prevent soil contamination
Spill Cleanup: Scoop or sweep up without generating excessive dust, place in labeled containers for disposal, ventilate area
Decontamination: Wash exposed area with water, launder or dispose of contaminated clothing based on company guidelines

Handling and Storage

Safe Handling: Use with adequate ventilation, avoid dust generation, wash hands before eating or drinking after use, use non-sparking tools if necessary
Storage Conditions: Store in a cool, dry, well-ventilated location, keep container tightly closed, protect from moisture, segregate from bases and oxidizers
Incompatible Materials: Strong oxidizing agents and strong bases, substances that react with organic acids
Hygiene Practice: Clean work area after handling, prevent contamination of food and beverages, keep containers clearly labeled

Exposure Controls and Personal Protection

Occupational Exposure Limits: No established limit for tartaric acid, avoid excessive exposure through general dust limits (often 10 mg/m3 for inhalable dust)
Engineering Controls: Use process enclosures, local exhaust ventilation, or other engineering controls to keep airborne levels below recommended exposure guidelines
Personal Protective Equipment: Chemical-resistant gloves, safety goggles or face shield, lab coat or apron, dust mask in case of limited ventilation
General Controls: Remove contaminated clothing, wash thoroughly after handling, avoid eating or drinking in the work area

Physical and Chemical Properties

Appearance: White crystalline powder
Odor: Odorless
Melting Point: Around 171 °C
Boiling Point: Decomposes before boiling
Density: About 1.76 g/cm³
Solubility: Readily dissolves in water, limited solubility in ethanol, nearly insoluble in ether
pH: 2.2 (5% water solution)
Vapor Pressure: Negligible at standard temperature
Partition Coefficient: Log Kow approximately -2 (strong hydrophilic character)
Other Properties: Not volatile, not self-reactive, non-combustible

Stability and Reactivity

Chemical Stability: Stable under normal storage and handling conditions
Conditions to Avoid: Excess moisture, heat above melting point, contact with incompatible materials
Material Incompatibility: Strong bases, alkalis, oxidizers
Hazardous Decomposition Products: Carbon oxides in case of fire or high-temperature breakdown
Potential Reactions: Decomposition from strong acids, bases, or oxidizers can yield hazardous fumes

Toxicological Information

Acute Toxicity: Oral LD50 in rats about 4,360 mg/kg, low toxicity to humans under normal use
Skin Irritation: Prolonged or repeated contact can cause mild irritation
Eye Effects: May cause moderate irritation or redness
Inhalation Effects: Dust may irritate the nose, throat, and respiratory tract, symptoms include coughing or discomfort
Sensitization: Not known to cause allergic sensitization
Long-term Exposure: No definitive evidence of carcinogenicity, mutagenicity, or reproductive toxicity from standard laboratory testing

Ecological Information

Aquatic Toxicity: Practically non-toxic to fish and aquatic invertebrates at environmental concentrations
Persistence and Degradability: Rapidly breaks down in the environment through microbial activity
Bioaccumulation: Does not bioaccumulate based on physical properties and degradation
Mobility: Highly soluble in water, may move through soil, not expected to linger in the environment
Other Effects: Large releases may cause localized pH shifts that could temporarily harm aquatic life

Disposal Considerations

Waste Disposal: Dispose in accordance with local, regional, and national regulations, typically as general laboratory or food processing waste
Container Disposal: Rinse thoroughly before recycling or discarding according to jurisdiction guidelines
Incineration: Incineration or landfill may be permitted, avoid releasing dust or fumes during disposal
Reuse and Recycling: If pure and uncontaminated, reuse for same applications whenever safe and allowed by local policy

Transport Information

UN Number: Not regulated as dangerous goods under UN Model Regulations
Proper Shipping Name: L-Tartaric Acid
Transport Hazard Class: Not classified for transport
Packing Group: None assigned, treat as non-hazardous
Transport Precautions: Keep package tightly sealed and dry, protect from moisture, prevent container breakage during transit
Regulatory Status: Non-dangerous under shipping regulations for land, sea, or air

Regulatory Information

TSCA Status: Listed in the United States Toxic Substances Control Act inventory
EINECS (EU): Listed (201-769-8)
Other National Inventories: Included in Canadian DSL, Australian AICS, Japanese ENCS
Labeling Requirements: Appropriate signal words, hazard statements, and precautionary details must be present under GHS regulations
Other Regulations: Safe for use in regulated concentrations in food, pharmaceutical, and industrial applications as permitted by authorities such as the FDA, EFSA, and Health Canada; workplace safety standards such as OSHA apply for manufacturing and handling