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The Story of Copper(II) Chloride Dihydrate: More Than Just a Blue-Green Salt

Historical Development

Copper compounds stretch far back through human history. The Egyptians used blue and green copper minerals in pigments, while early metallurgists refined copper into bronze. Copper(II) chloride, especially the dihydrate form known for its striking blue-green color, found a defined place in the 19th century during the growth of industrial chemistry. Chemists figured out how to reliably prepare and purify it. They paid close attention to its reactivity and solubility, making it a staple for labs from the Victorian era onward. The product's journey wasn’t just about being another salt—it became a window into understanding ionic solutions, color changes, and the way transition metals interact with water and other chemicals.

Product Overview

Copper(II) chloride dihydrate landed on my chemistry bench as a challenge and a curiosity. Its glittering, bluish-green crystals drew attention, but its importance showed up in how it played with other elements. It represents copper in a +2 oxidation state, giving it a definite role in both teaching and industrial settings. Unlike some copper salts that hang around in the shadows, copper(II) chloride jumps out due to its vivid color, making it an easy visual marker in experiments and demonstrations. Over time, it gained credibility among chemists for both its unique properties and its dependability in a range of reactions.

Physical & Chemical Properties

Touching, smelling, and observing copper(II) chloride dihydrate narrows science down to experience. The salt melts to the touch and laces the air with a light copper tang. Soluble in water, these blue-green crystals dissolve quickly, releasing two moles of water for each formula unit, a feature that defines much of its behavior. With a melting point just high enough to keep it stable on the shelf but low enough to let it break down when heated, it becomes a handy tool for both demonstrating dehydration and examining hydrate chemistry. As a strong oxidizer, it reacts with metals like aluminum and zinc, creating everything from hydrogen bubbles to flamboyant copper coatings. Add to this the fact that its color shifts with concentration and environment, and you have a material impossible to ignore.

Technical Specifications & Labeling

Clarity about what's in the bottle has always mattered. Whether for a high school teacher in Illinois or a research chemist in Berlin, correct labeling ensures safe and accurate use. I remember reading hand-written labels faded by years on ancient amber bottles—sometimes giving only the Latin, sometimes showing chemical formulas. In modern times, we see detailed purity percentages, batch numbers, and lot codes on industrial containers. Reliable suppliers provide labels that state the correct dihydrate form, molecular mass, and safety notations according to international standards, reducing mix-ups that could trip up experiments or, worse, add to lab hazards.

Preparation Method

Making copper(II) chloride dihydrate is a chemistry rite of passage. Pouring hydrochloric acid over copper(II) oxide, waiting for that telltale blue-green solution, then carefully evaporating the liquid to coax out perfect crystals—each step reveals lessons in reaction control, solubility, and patience. Old laboratory manuals detail the risks of vigorous hydrogen chloride gas production, offering personal stories about learning lab discipline under the sharp eye of a seasoned instructor. In large-scale manufacturing, companies stick close to similar reactions, adjusting for purity and environmental safety. Every batch carries the fingerprint of chemistry-in-action, showing how control over reaction conditions shapes everything from crystal size to residual contamination.

Chemical Reactions & Modifications

If you want action in a test tube, copper(II) chloride delivers. Dropping aluminum foil in a solution leads to a fizzing, copper-plating dance that never fails to ignite interest. This reaction demonstrates not just redox chemistry but also the thrill of discovery for anyone new to the lab. Copper(II) chloride takes center stage in organic chemistry as well, serving as a catalyst for chlorination reactions and even helping chase down elusive intermediates in complex syntheses. Its role in forming complexes with ammonia offers a direct lesson about ligand exchange, which moves from school labs straight into real-world industrial processes.

Synonyms & Product Names

Chemists live with a dizzying array of synonyms and naming conventions: cupric chloride, copper dichloride, and the trihydrate or anhydrous forms can trip up newcomers. The full IUPAC name gets ignored in casual use, but clarity sticks when it matters; misunderstanding chemical names can mean ruined experiments or worse. In print and conversation, abbreviations like CuCl2·2H2O communicate volumes to those who know the code. "Copper(II) chloride dihydrate" speaks to anyone who has looked for the correct form among a sea of seemingly similar compounds in a cluttered store cupboard.

Safety & Operational Standards

Handling copper(II) chloride dihydrate has always carried responsibility. In my time wading through chemical stockrooms, safety glasses and gloves weren’t negotiable. The compound's toxicity to humans, despite its low volatility, makes good ventilation mandatory. Contact with skin stings, while inhaling dust or splashes in the eye leads to big problems. Storage away from combustibles, acids, and anything that it could violently react with keeps hazards in check. Good labeling and clear protocols, based on lessons learned from decades of both accidents and rigorous training, reduce the risk to manageable levels. The rules owe as much to real-world slip-ups as to formal regulations, underscoring why chemical literacy is never optional.

Application Area

Use copper(II) chloride dihydrate in a lab and you start to appreciate its reach. In analytical chemistry, titrations show off its color as a pH or oxidation indicator. In organic labs, it catalyzes reactions that speed up industrial processes, lowering energy costs and waste. Textiles rely on copper(II) chloride for dyeing and printing; its use in tin etching for circuit boards gives electronics a subtle but essential boost. Environmental scientists use the salt to trace copper in water samples, revealing pollution patterns or verifying cleanup efforts. Each application threads copper(II) chloride further into both industrial and scientific worlds, far removed from the classroom experiments that first ignite interest.

Research & Development

Chemistry never stops moving. Researchers dig deeper into copper(II) chloride’s hidden capabilities, seeking new catalysts and environmental uses. Studies into less toxic analogs or more easily recyclable salts gain funding each year. In academic labs, students investigate copper(II) chloride’s role in electrochemistry, opening doors for sustainable battery technology. Recent experiments pursue the compound’s ability to mediate nano-assembly or shed light on complex coordination chemistry, pushing boundaries for green chemistry and materials science. I’ve seen research teams rely on its consistency as a benchmark, returning to this salt whenever they needed reliable, well-understood behavior. As new technologies develop, copper(II) chloride’s toolkit continues to expand.

Toxicity Research

Concern about copper(II) chloride’s safety isn’t just theoretical. Studies link copper exposure to both acute and chronic health effects, especially with repeated contact or ingestion. Researchers track its toxic action on liver and kidney tissue—both in animal studies and, through epidemiological work, in affected populations. Environmental questions loom large, since copper salts leach into soils and waterways, affecting plant and aquatic life. An honest reading of the toxicology tells a story where carelessness has real consequences, both for handlers and the environment. Waste water treatment plants and manufacturers take part in ongoing efforts to reduce accidental release or contamination, sometimes facing public scrutiny. Institutions insist on clear protocols, not just to avoid citation, but because case studies and lab incidents read out the risks in painful detail.

Future Prospects

Looking ahead, copper(II) chloride dihydrate has a future bound tightly to both regulation and innovation. Industry pushes for ways to recycle copper compounds and cut down on hazardous waste. Clean energy initiatives consider its potential role in battery development and efficient catalysis. Advances in analytical chemistry may give new purpose to copper compounds in water quality monitoring and industrial process control. Training programs include it as a cornerstone of practical chemical education, especially as an example of how careful, respectful handling pays off. Transparent research, open debate about risks, and creative new applications will likely chart the path for copper(II) chloride dihydrate, evidence that even the oldest salts contain surprises for anyone willing to keep asking questions.




What is the chemical formula of Copper(II) Chloride Dihydrate?

Unlocking the Formula: CuCl2·2H2O

Everyday substances often have complex backgrounds, and Copper(II) chloride dihydrate is no different. Many people know it by its striking blue-green color in a classroom setting or lab experiment, but let’s get real — the chemical formula, CuCl2·2H2O, actually means something for everyone who works with materials, soil chemistry, or even art conservation. It’s not just a bunch of letters and numbers. That little dot in the formula isn’t decoration; it shows two water molecules join the copper chloride party, fundamentally changing its properties.

Why Should Anyone Care About Hydration?

Chemistry textbooks talk about hydrates, but for those of us who’ve had a handful of lab sessions or handled this stuff outdoors, you learn quickly that dihydrate can’t take rough storage. Set it out in the open air and the water starts to disappear, leaving the material dry and less effective for experiments or industrial work. That clicked for me the day I returned to a shelf and saw my sample had changed color after a careless move left it exposed. If you’re using it to teach stoichiometry or pull off an elegant crystallization, that water matters — a dry, anhydrous version won’t cut it if your equation expects CuCl2·2H2O.

Beyond the Classroom: Real Impact

Let’s talk about how this substance pops up in the wild. Water treatment relies on copper compounds to remove irritating algae. Depending on the region, the dihydrate might be shipped instead of the anhydrous form because it’s safer and dissolves quicker thanks to the water built in. I’ve witnessed how a pile of blue-green powder clears a pond after stubborn algae blooms. Without correct measurements, there’s a risk to fish and plants. Nothing quite wakes you up like a call from an unhappy groundskeeper who got a chemistry lesson the hard way.

Solutions: Handling and Information Gaps

Plenty of problems show up from plain old confusion. Sometimes, suppliers list Copper(II) chloride without highlighting the extra water, making folks on the ground misjudge how much chemical is actually copper chloride versus water. It’s easy to fix if manufacturers and distributors clearly state the formula on packaging. Good labeling saves time, money, and prevents headaches. In labs, instructors should stress the difference between forms with demos using both types. That lesson stuck with me after sorting contaminated samples because a student grabbed the wrong compound off the shelf. Hands-on examples do a better job than any lecture could.

Fact-Based Use Leads to Better Results

The National Institute for Occupational Safety and Health (NIOSH) and other safety organizations flag Copper(II) chloride dihydrate as an irritant. Students and staff should glove up and use protective eyewear because the risks aren’t just a theoretical talking point. From acute exposure reports, rashes and eye burns are not rare. I’ve seen too many people skip a face mask, only to deal with the consequences after an accident in the stockroom. Sticking to the real chemical formula and respecting safety sheets doesn’t slow progress — it keeps everyone healthy enough to keep doing the science.

What are the common uses of Copper(II) Chloride Dihydrate?

Chemical Labs and Learning

Copper(II) chloride dihydrate shows up early in most chemistry classrooms. Its bright blue-green crystals catch the eye, but the real draw lies in its use during fundamental experiments. In student labs, teachers count on it for redox reactions. It becomes the basis for lessons involving the transformation between copper and its ions, making abstract textbook concepts tangible. Lab work with copper compounds trains future scientists, showing real cause and effect—copper turns from solid to blue liquid, then back again. The experience helps me trust classroom learning since what I see is real.

Dyeing and Printing Fabrics

The textile industry turns to copper(II) chloride dihydrate for coloring fabrics and for printing designs. In smaller dye shops, it creates shades not easily achieved with organic dyes. Cotton and viscose wear these colors well; the process gives a unique hue and improves staying power. Textile workers tell stories about the richness and lasting quality, giving customers a reason to come back. There’s an art to it, though: too much and the fabric weakens, too little and the result looks dull. Balancing technique and reliable supply keeps textile businesses running profitably.

Electronics Manufacturing

Copper etching relies on copper(II) chloride dihydrate. Printed circuit board (PCB) producers use it to carve away unwanted copper, leaving behind thin conducting pathways that power electronics. Workers mix it into a bath, immerse a copper-coated board, and watch precise tracks emerge. This process feeds modern tech from simple radios to advanced smart devices. As wearable gadgets and IoT gear grow more common, factories look for safer disposal and recycling systems to limit copper runoff. My visits to PCB plants always include talks about balancing efficiency with environmental responsibility.

Photography’s Forgotten Helper

Before digital took over, photographers relied on copper(II) chloride dihydrate for certain film-developing routines. It delivered the subtle coloring found in sepia or toned images. Darkrooms made space for jars of this stuff among stop baths and fixers. Some analog enthusiasts still keep the tradition alive, trading recipes on forums. The hands-on craft means dirty fingers, ticklish smells, and unpredictable results—something phone cameras can’t quite reproduce. Film labs that still operate today keep copper compounds locked up, mindful of waste, but appreciate what they do for their art.

Chemical Synthesis on the Factory Floor

Factories producing other chemicals often reach for copper(II) chloride dihydrate as a catalyst or reactant. It helps build pharmaceutical intermediates, acts in the recovery of precious metals, and launches reactions in organic chemistry. The familiar blue hydrate means faster, cleaner results than other copper salts. Chemical engineers trust it for reliability in batch processing and pilot-scale runs. In regulated workplaces, the safety manager looks out for spills, so workers get regular training in containment and cleanup. My experience on this side of the business showed me how a single chemical, handled right, becomes essential without drawing much attention.

Wastewater Treatment and Public Health

Copper(II) chloride dihydrate plays a role in water care. Some facilities use it to control fungal and algal growth, especially in cooling towers and closed water systems. It’s not a catchall solution—regulation means precise dosing, constant measurement, and a clear disposal plan. Maintenance crews appreciate how a little goes a long way, but local authorities keep a sharp eye on runoff. Too much copper in rivers causes problems for fish and other life. My time on a city water committee highlighted the constant debate between effectiveness and ecological limits.

Balancing Act and Next Steps

More companies now invest in greener chemistry. Substitutes exist for some processes, but none offer copper(II) chloride dihydrate’s mix of cost, color, and reliability. Schools need safer storage, tech plants improve recycling, and water managers must keep public trust. Every use, from dye shops to labs, tells the same story—efficiency counts, but so does keeping harm in check.

How should Copper(II) Chloride Dihydrate be stored?

The Risks in the Open Air

Copper(II) chloride dihydrate looks harmless at a glance—a blue-green solid, handy in labs and chemical classrooms. Yet, appearances can fool you. Anyone handling it too casually soon sees trouble. I remember my college days, watching students who didn’t reseal the jar properly. After a week, the crystals grew damp and started clumping together. This chemical grabs moisture from the air like a sponge. Leave it out too long or in the wrong atmosphere, and you find a sticky mess instead of tidy powder. This isn’t just annoying. Moisture can break down the compound, making it less effective for experiments or technical work. Exposure to air brings another headache: it interacts with oxygen, leading to gradual decomposition. Once its color shifts or strange odors come off, the stuff inside the bottle can’t be trusted.

Health Hazards are Real

It doesn’t take a scientist to spot the danger. This salt is toxic if swallowed or inhaled. Getting any of it on your skin can cause irritation, or worse if it lingers. Once, a lab mate didn’t notice a tiny crack in the storage container—pretty soon, the crystals dried his hands out and left a rash. With kids or pets running around at home, or when the stuff is on a shelf next to other food containers, the risk multiplies. Some people, hearing “di-hydrate,” think it’s not so hazardous. Never make that mistake. This compound draws water as well as trouble.

How Good Storage Works

Everyone who has used copper(II) chloride dihydrate for metal etching or chemistry knows the right storage makes a huge difference. Keep it in air-tight containers, preferably glass or high-quality plastic that can’t react with the salt. Screw-cap jars seal out moisture and block that green-blue dust from escaping. Stick a clear and unmistakable label on the front, including hazard symbols and the date you bought it. Don’t store it anywhere the temperature swings up and down—pick a space cool and shaded. Direct sunlight bakes the substance and speeds up breakdown, ruining the chemical for future use.

If there’s even a slight leak, clean it up using gloves and goggles. Check the storage area for powder or crystalline dust every now and then. Replace containers before cracks or flaws give you bigger headaches. In shared spaces like schools or community labs, don’t skip the sign-in sheet. Track who took out the bottle, so you never lose track or leave the compound exposed.

Safety Precautions

Anyone handling copper(II) chloride dihydrate ought to treat it seriously. That means wearing gloves, lab coats, and eye protection, not as a suggestion but as habit. Keep the chemical away from anything edible or drinkable. Never use food containers for storage. Lay out clear protocols for accidental spills—baking soda neutralizes strong acids, but won’t make this compound safe. Dispose of waste through registered hazardous waste services. In my experience, trying DIY disposal leads to ugly stains or, worse, environmental violations.

Building a Culture of Accountability

Too many labs slip up because someone figured a “quick fix” is fine for one afternoon. Copper(II) chloride dihydrate is unforgiving. Lax habits endanger people and ruin expensive supplies. Real accountability grows when everyone gets the right training, has easy access to data sheets, and can openly call out sloppy practice. A well-run workspace stays safe, productive, and ready for real learning and discovery—without nasty surprises in the chemical store.

Is Copper(II) Chloride Dihydrate hazardous to health?

What Actually Is Copper(II) Chloride Dihydrate?

Copper(II) chloride dihydrate, a blue-green crystalline compound, turns up in classrooms, laboratories, and even in some industrial settings. Chemists grab it off the shelf to run some classic demonstrations, like the beautiful blue flames in flame tests. Its chemical formula is CuCl2·2H2O. You’ll spot it in etching solutions and pigment work, and folks even use it in some photographic processing. It may seem like one of the safer salts, but, as any chem teacher will tell you, appearances don’t always tell the full story.

Why Does It Raise Health Concerns?

Anyone who has spilled a little bit on their skin knows it’s not just another table salt. If it touches the skin or eyes, copper(II) chloride dihydrate can cause irritation — stinging, redness, maybe even a rash. Inhalation brings its own problems: fine dust rises up, gets into your airways, and starts irritating the nose, throat, and lungs. I remember a colleague working with a similar copper salt who ignored the dust while weighing out powder. Within half an hour, sneezing and throat scratching set in.

If someone swallows a bit by accident, stomach pain, vomiting, and diarrhea can follow. Some toxicity stems from the copper ion itself, which the body can’t get rid of quickly in high amounts. In rare and more severe cases, copper poisoning gets much worse—kidney and liver issues don’t stay out of the picture for long. The National Institute for Occupational Safety and Health places copper salts firmly in their eye as hazardous, with plenty of data linking copper exposure over time to serious health problems. The World Health Organization keeps copper under review in drinking water because, even at low levels, copper sticks around and accumulates.

Understanding the Bigger Picture

The disregard for chemical safety in home science experiments sometimes opens the door for trouble. With YouTube chemistry tutorials showing off the blue-green color, people get curious without thinking about gloves or goggles. Even in professional settings, it’s easy for someone to forget to use a dust mask. One slip, then a handful of people start coughing, or someone ends up with a red, irritated patch of skin that stings for days.

Some might shrug off the warnings and argue that plenty of salts cause irritation. That misses the real point: copper(II) chloride dihydrate is not in the same league as NaCl, and frequent exposure isn’t safe, especially for children or pets who might get curious and touch or taste something they find on a countertop. I once watched an incident unfold at a science fair where a jar of copper(II) chloride sat unlabeled on a table. By the end of the afternoon, two people had handled it with bare hands—neither had any clue they were skipping basic safety.

Practical Solutions for Handling Safely

The rules are simple, yet they get overlooked. Wear gloves, goggles, and work with good ventilation. Always wash up well when finishing a project. Store copper(II) chloride dihydrate away from areas where food, drinks, or kids gather. Label containers clearly and keep them out of reach if you teach or experiment at home. Dispose of waste with guidance from local hazardous waste programs. Schools and labs should stick to the most up-to-date safety protocols, keeping safety data sheets on hand and providing training before using any copper compounds.

Copper(II) chloride dihydrate demands respect, not fear. Staying informed, taking the right precautions, and educating those around us make hands-on science safer—without missing out on the excitement that chemistry can bring.

What is the appearance and color of Copper(II) Chloride Dihydrate?

Seeing It For Yourself

Copper(II) chloride dihydrate falls into that group of chemicals you won’t easily mistake for something else. Drop some crystals onto a white bench and a bright, almost electric, blue-green calls out for attention. It’s not the muted green of weathered bronze or the deep blue you might find in copper sulphate; this is a hue that grabs daylight and seems to glow from within. That unique turquoise-green shade pops, thanks to copper ions mingling with water molecules attached to every formula unit.

Anyone who’s held a bottle of this stuff in a school lab or stockroom remembers it. It’s crystalline, like chunky rock salt, but shards break off with jagged edges instead of neat cubes. In some bottles, larger pieces look almost translucent. If you tip the bottle or just leave it in the air, the surface picks up a powdery, paler tinge as it starts to dry out—something that says, “Hey, I contain water, and I’ll lose it if you don’t cap me properly.”

Chemical Backstory and Classroom Moments

Copper compounds stand out for people just learning chemistry, and copper(II) chloride dihydrate is part of that experience. In many science lessons, teachers use it to explain hydration and color in transition metals. The water bound to the copper gives this hydrated form its signature blue-green. Leave it open in a dry setting—a warm storeroom, say—and the crystals lose that water over time, turning olive brown as they dehydrate. That shift can surprise a student who expects chemistry to be stable neatly tucked in the cupboard.

Seeing this color change gives a hands-on lesson about the effect water molecules have on structure and appearance. You only need a bit of humidity to keep the stunning green alive. In some parts of the world where labs don’t use air conditioning, color shifts in copper(II) chloride jars provide a real warning about careless storage.

Safety and Storage: More Than Just Looks

Looks tell part of the story, but safety matters too. The striking color can tempt the curious, and it’s easy to underestimate the hazards in plain sight. Copper(II) chloride dihydrate can cause skin and eye irritation. Accidental spills are rare, but most people who’ve worked around a cluttered prep bench know a drop of moisture on the label can smudge critical information, or a forgotten spatula can leave powdery stains that won’t wash out from your coat.

There’s a reason experienced lab techs stress clear labeling and dry storage. Damp air leads to clumped bottles; dry air strips away color and turns spill powder more airborne. Keeping the product in tightly sealed containers and using gloves is standard procedure not just for peace of mind but because copper ions travel fast—leaving reminders on hands and glassware long after the class is over.

Extra care with disposal matters too. Some teachers pour leftovers into waste containers meant for hazardous chemicals, not down the sink, because copper can cause environmental damage, staining pipes and harming aquatic life even at low concentrations. Good chemical management keeps everyone safe and the colors where they belong—in the bottle and not in the waterways.

Why This Matters Beyond the Lab

You spot copper(II) chloride dihydrate in the field as well, especially in pigment making and certain industrial etching processes. Color serves as an unmistakable signal; chemists rely on those familiar green-blue crystals to make sure the job’s on track and the workspace safe. Recognizing this compound by sight brings back a wave of lab experiences and reminds you that the bright, watery shade isn’t just eye candy—it’s a sign of copper in its hydrated state, paired with a need for solid care and chemical respect.

Copper(II) Chloride Dihydrate
Names
Preferred IUPAC name Copper(II) chloride dihydrate
Other names Cupric chloride dihydrate
Copper dichloride dihydrate
Copper(2+) chloride dihydrate
Pronunciation /ˈkɒpər tuː ˈklɔːraɪd daɪˈhaɪdreɪt/
Identifiers
CAS Number 10125-13-0
3D model (JSmol) `CU(CL)2.2H2O`
Beilstein Reference 358718
ChEBI CHEBI:86155
ChEMBL CHEMBL1379070
ChemSpider 54649
DrugBank DB11140
ECHA InfoCard 03d066a0-eb7e-4140-86dd-c6c878488454
EC Number 231-210-2
Gmelin Reference 63568
KEGG C00244
MeSH D017602
PubChem CID 24852960
RTECS number GL6910000
UNII 89GF1H8ZQO
UN number UN2802
Properties
Chemical formula CuCl₂·2H₂O
Molar mass 170.48 g/mol
Appearance Blue-green crystalline solid
Odor Odorless
Density 2.51 g/cm³
Solubility in water 75.7 g/100 mL (0 °C)
log P -1.027
Acidity (pKa) 6.5
Basicity (pKb) 6.99
Magnetic susceptibility (χ) +60.0·10⁻⁶ cm³/mol
Refractive index (nD) 1.925
Viscosity Viscous crystalline solid
Dipole moment 1.98 D
Thermochemistry
Std molar entropy (S⦵298) 110.0 J⋅mol⁻¹⋅K⁻¹
Std enthalpy of formation (ΔfH⦵298) -771.4 kJ/mol
Pharmacology
ATC code V07AV03
Hazards
Main hazards Harmful if swallowed, causes skin and eye irritation, may cause respiratory irritation.
GHS labelling GHS05, GHS07
Pictograms GHS05,GHS07
Signal word Warning
Hazard statements H302 + H315 + H319 + H335
Precautionary statements Precautionary statements: "Wash hands thoroughly after handling. Do not eat, drink or smoke when using this product. IF SWALLOWED: Call a POISON CENTER or doctor/physician if you feel unwell. Rinse mouth. Avoid release to the environment.
Lethal dose or concentration LD50 Oral Rat 140 mg/kg
LD50 (median dose) LD50 (median dose): Oral, Rat: 584 mg/kg
PEL (Permissible) PEL: 1 mg/m³
REL (Recommended) 0.01 mg(Cu)/m³
IDLH (Immediate danger) No IDLH established.
Related compounds
Related compounds Copper(II) chloride
Copper(I) chloride
Copper(II) sulfate
Copper(II) nitrate