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Material Safety Data Sheet for Chloramine T Trihydrate

Identification

Product Name: Chloramine T Trihydrate
Chemical Formula: C7H7ClNNaO2S·3H2O
CAS Number: 7080-50-4
Synonyms: Sodium P-toluenesulfonchloramide Trihydrate, N-Chloro-p-toluenesulfonamide sodium salt, Tosylchloramide sodium
Recommended Uses: Disinfectant, reagent for laboratory and industrial applications, microbiological testing
Supplier: Located on shipping documentation and invoices
Emergency Contact: Found on supplier Safety line and shipping manifest

Hazard Identification

GHS Classification: Acute toxicity (oral, dermal, inhalation), Eye irritation, Specific target organ toxicity (single exposure), Skin irritation
Signal Word: Warning
Hazard Statements: Harmful if swallowed, causes skin irritation, causes serious eye irritation, may cause respiratory irritation
Pictograms: Exclamation mark
Precautionary Statements: Avoid contact with skin and eyes, use only in well-ventilated areas, wear protective equipment, wash hands after handling
Potential Health Effects: Inhalation leads to respiratory tract irritation, ingestion produces gastrointestinal distress, contact brings about skin and eye damage

Composition / Information on Ingredients

Chemical Name: Chloramine T Trihydrate
Concentration: 98–100%
CAS Number: 7080-50-4
EC Number: 204-854-7
Impurities and Stabilizing Additives: Minor traces of sodium chloride as byproduct, no significant impact to hazard

First Aid Measures

Inhalation: Remove to fresh air immediately, support breathing if symptoms develop, contact a physician
Eye Contact: Rinse eyes carefully with water for 15 minutes, lift upper and lower eyelids, seek medical attention
Skin Contact: Remove contaminated clothing, wash exposed area with soap and water generously, medical care if symptoms persist
Ingestion: Rinse mouth, do not force vomit, call poison control or medical help at once, provide water if conscious
Most Important Symptoms: Eye pain, redness or blurred vision, coughing, burning sensation in throat or nose, abdominal pain if ingested

Fire-Fighting Measures

Suitable Extinguishing Media: Dry chemical powder, carbon dioxide, alcohol-resistant foam, do not use water streams on surrounding chemical fires
Fire Hazards: Releases toxic fumes of nitrogen oxides, sulfur oxides, hydrochloric acid and chlorine, also risks sodium oxide ash
Specific Protective Actions: Firefighters put on self-contained breathing apparatus and wear full protective gear, cool exposed containers with water spray
Explosion Data: Not explosive under normal handling, may intensify fire with reactive agents
Further Advice: Remove personnel from area, ensure adequate ventilation after fire extinguishes

Accidental Release Measures

Personal Precautions: Wear gloves, chemical goggles, long sleeves and respirator as needed
Environmental Precautions: Prevent entry into drains, waterways and soil, isolate spill with diking as necessary
Cleanup Methods: Scoop or sweep solid material into appropriate chemical-waste container, ventilate affected area, wash spill site after removal
Other Advice: Use non-sparking or anti-static tools, avoid dust formation while cleaning

Handling and Storage

Handling: Keep container tightly sealed, open containers with care under local ventilation, minimize breathing in dust, avoid touch with skin or eyes, restrict access to trained individuals only
Storage: Place in cool, dry, well-ventilated space well apart from acids or reducing agents, keep away from moisture and incompatible materials, label containers clearly and keep away from food or drink
Storage Temperature: Store between 2°C and 8°C prevents decomposition, protect from sunlight and strong light sources
Packaging Materials: Use high-density polyethylene, glass, or compatible chemical-resistant drums

Exposure Controls and Personal Protection

Occupational Exposure Limits: No specific OSHA or ACGIH values, minimize inhalation and contact at all times
Engineering Controls: Work in chemical fume hood or local exhaust system
Personal Protective Equipment: Chemical-resistant gloves (nitrile or neoprene), splash-proof goggles, lab coat, respirator with P2 particulate filters if dust risk present
Other Protection: Eye-wash stations and safety showers required close to work site, wash hands before eating or drinking

Physical and Chemical Properties

Appearance: White to slightly off-white crystalline powder
Odor: Weak chlorine-like odour
Molecular Weight: 281.72 g/mol
pH: 8.5–10.5 (1% solution at 20°C)
Melting Point: Decomposes above 170°C
Solubility: Highly soluble in water, partially soluble in ethanol
Boiling Point: Not applicable (decomposes)
Vapor Pressure: Negligible at room temperature
Relative Density: 1.45 (bulk)
Flash Point: Not applicable to solid
Partition Coefficient: Not determined
Decomposition Products: Chlorine, hydrogen chloride, nitrogen oxides, toluene sulfonic acid

Stability and Reactivity

Chemical Stability: Stable under recommended conditions, moisture or heat accelerates decomposition
Reactivity: Strong oxidizer, reacts vigorously with acids, reducing agents, ammonium or organic material
Hazardous Reactions: Reacts to produce toxic gases with acid or heat
Incompatible Materials: Acids, reducing chemicals, combustible materials, metals, ammonium salts
Hazardous Decomposition: Emits corrosive vapors of chlorine, hydrochloric acid, sulfur oxides upon thermal decomposition

Toxicological Information

Acute Toxicity: Harmful by oral (LD50 rat ~2600 mg/kg), low toxicity by dermal route, toxic by inhalation of dust
Skin Corrosion/Irritation: Causes skin irritation and redness on contact
Eye Damage/Irritation: Causes strong pain, lesions, prolonged watering, redness
Respiratory Sensitization: Coughing, throat irritation, difficulty breathing in sensitive individuals
Carcinogenicity: Not classified as carcinogenic by IARC, NTP or OSHA
Other Data: No known reproductive, mutagenic or chronic toxicity concerns in scientific literature at standard exposures

Ecological Information

Ecotoxicity: Toxic to aquatic life, severe short-term effects on fish, invertebrates and algae, do not allow product or rinse water to enter drains
Persistence and Degradability: Undergoes abiotic degradation in water, stable in storage for long periods without light or heat exposure
Bioaccumulation: Not likely to persist or bioaccumulate in food chain at standard concentrations
Mobility in Soil: Dissolves easily, moves through soil with water, greater risk in sandy or coarse substrates
Other Adverse Effects: Promotes eutrophication if released in quantity, avoid spills close to lakes, rivers and public waterways

Disposal Considerations

Disposal Methods: Dispose unused product and contaminated containers via licensed chemical waste contractor, dilute large spills and neutralize slowly with sodium sulfite or thiosulfate before discharge (subject to regulations)
Sewage Disposal: Never flush in sewage or septic tanks, do not mix with household garbage
Contaminated Packaging: Decontaminate containers by triple rinsing, puncture to prevent re-use, send for professional disposal
Additional Guidance: Consult local, regional and national hazardous waste disposal regulations for full compliance

Transport Information

UN Number: 3263
Proper Shipping Name: Corrosive solid, basic, organic, n.o.s. (contains Chloramine T Trihydrate)
Transport Hazard Class: 8 (Corrosive Materials)
Packing Group: III
Transport Labels: Corrosive, Marine Pollutant if shipped in bulk
Special Precautions: Secure packages upright, shield from impact or exposure to moisture in transit, notify warehousing teams of contents
Limitations: Not permitted on passenger aircraft in most jurisdictions, only as cargo with proper documentation

Regulatory Information

TSCA: Listed on US Toxic Substances Control Act inventory
REACH: Registered in compliance with European community regulation, restrictions on bulk handling
OSHA: Subject to Hazard Communication Standard, mandatory labeling and safety documentation
WHMIS: Controlled product under Canadian WHMIS, classified as Class D2B (Toxic) and E (Corrosive)
Other Regulation: Covered by local hazardous materials standards, not scheduled under international narcotics codes, subject to aquatic toxicity warnings